TY - JOUR
T1 - XMCD at the LII,III edges of Er in ErMn2, ErFe 2, ErCo2, ErNi2, and ErAl2 laves phases and in Er2(SO4)3, 8H20
AU - Giorgetti, Christine
AU - Dartyge, Elisabeth
AU - Baudelet, François
AU - Galéra, Rose Marie
PY - 2004/7/1
Y1 - 2004/7/1
N2 - X-ray magnetic circular dichroism (XMCD) measurements have been performed at the LII,III edges of Er in the intermetallic compounds ErMn 2, ErFe2, ErCo2, ErNi2, and ErAl2, as well as in the ionic compound Er2(SO 4)3,8H20, in order to study the evolution of the XMCD spectra as a function of the 5d states filling and/or their hybridization with magnetic or nonmagnetic electronic states. Almost all the spectra present the same general features, confirming that the 4f-5d intra-atomic coupling is a key point to explain XMCD spectra. Thus, we analyze the models based on this interaction, proposed to account for the unexpected sign of E1 -XMCD measurements, as well as the nonstatistical branching ratio between XMCD at the LII and LIII edges. We underline the impossibilities of reproducing our measurements using these models. Moreover, we point out the special role played by Fe which leads, at the LII edge of Er, to a significant modification of the shape of XMCD spectrum and an unexpected temperature dependence. The XMCD revealed an unexpected behavior of the 5d magnetic polarization in these compounds which is not visible in macroscopic measurements. This also demonstrates the non-negligible role played by the 5d-3d hybridization.
AB - X-ray magnetic circular dichroism (XMCD) measurements have been performed at the LII,III edges of Er in the intermetallic compounds ErMn 2, ErFe2, ErCo2, ErNi2, and ErAl2, as well as in the ionic compound Er2(SO 4)3,8H20, in order to study the evolution of the XMCD spectra as a function of the 5d states filling and/or their hybridization with magnetic or nonmagnetic electronic states. Almost all the spectra present the same general features, confirming that the 4f-5d intra-atomic coupling is a key point to explain XMCD spectra. Thus, we analyze the models based on this interaction, proposed to account for the unexpected sign of E1 -XMCD measurements, as well as the nonstatistical branching ratio between XMCD at the LII and LIII edges. We underline the impossibilities of reproducing our measurements using these models. Moreover, we point out the special role played by Fe which leads, at the LII edge of Er, to a significant modification of the shape of XMCD spectrum and an unexpected temperature dependence. The XMCD revealed an unexpected behavior of the 5d magnetic polarization in these compounds which is not visible in macroscopic measurements. This also demonstrates the non-negligible role played by the 5d-3d hybridization.
U2 - 10.1103/PhysRevB.70.035105
DO - 10.1103/PhysRevB.70.035105
M3 - Article
AN - SCOPUS:42749099610
SN - 1098-0121
VL - 70
SP - 035105-1-035105-12
JO - Physical Review B - Condensed Matter and Materials Physics
JF - Physical Review B - Condensed Matter and Materials Physics
IS - 3
M1 - 035105
ER -