Résumé
Oligothiophenes carrying an alkylthiol group on one of the internal β-positions have been synthesized and adsorbed onto platinum and gold. The adsorbed assemblies are not very well organized, probably due to the geometry of the single molecules. The thiophene-based layers exhibit electrochemical activity in non aqueous electrolytes. The monomer units within the layers can be polymerized by a single anodic sweep. The obtained polymers show a high electrochemical and thermal stability. In some cases the polymer shows an increase of the structural order compared to the monomer layers.
| langue originale | Anglais |
|---|---|
| Pages (de - à) | 5-6 |
| Nombre de pages | 2 |
| journal | Synthetic Metals |
| Volume | 101 |
| Numéro de publication | 1 |
| Les DOIs | |
| état | Publié - 1 janv. 1999 |
| Evénement | Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier Durée: 12 juil. 1998 → 18 juil. 1998 |
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