β irradiation in borosilicate glasses: The role of the mixed alkali effect

N. Ollier; B. Boizot; B. Reynard; D. Ghaleb; G. Petite

doi:10.1016/j.nimb.2003.12.014

β irradiation in borosilicate glasses: The role of the mixed alkali effect

N. Ollier
, B. Boizot
, B. Reynard
, D. Ghaleb
, G. Petite

Laboratoire des Solides Irradiés
CNRS
Lab. Etudes du Comport. a Long Terme
CEA Marcoule, DTCD SECM

Résultats de recherche: Contribution à un journal › Article de conférence › Revue par des pairs

49 Citations (Scopus)

Résumé

Two series of mixed alkali borosilicate glasses have been studied (Na/K and Na/Li) in order to examine the mixed alkali effect influence on the structure evolution of β-irradiated glasses. In both glass series, paramagnetic defects concentration shows a non-linear variation with Na content. The defect nature is also affected and more particularly boron oxygen hole center versus oxygen hole center relative proportion. By Raman spectroscopy, we showed that polymerization increase and molecular oxygen production, linked to the alkali migration, were minimized for some irradiated glass compositions. Mixed alkali effect blocks structural changes under electron irradiation in Na/Li glasses while for Na/K glasses, structural evolutions are smaller than in pure alkali glasses but non-completely annihilated.

langue originale	Anglais
Pages (de - à)	176-182
Nombre de pages	7
journal	Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms
Volume	218
Numéro de publication	1-4
Les DOIs	https://doi.org/10.1016/j.nimb.2003.12.014
état	Publié - 1 juin 2004
Modification externe	Oui
Evénement	Proceedings of the Twelfth International Conference on Radiation - Gramado, Brésil Durée: 31 août 2003 → 5 sept. 2003

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10.1016/j.nimb.2003.12.014

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@article{55b24a8077a94da5b789149752d3ea9e,

title = "β irradiation in borosilicate glasses: The role of the mixed alkali effect",

abstract = "Two series of mixed alkali borosilicate glasses have been studied (Na/K and Na/Li) in order to examine the mixed alkali effect influence on the structure evolution of β-irradiated glasses. In both glass series, paramagnetic defects concentration shows a non-linear variation with Na content. The defect nature is also affected and more particularly boron oxygen hole center versus oxygen hole center relative proportion. By Raman spectroscopy, we showed that polymerization increase and molecular oxygen production, linked to the alkali migration, were minimized for some irradiated glass compositions. Mixed alkali effect blocks structural changes under electron irradiation in Na/Li glasses while for Na/K glasses, structural evolutions are smaller than in pure alkali glasses but non-completely annihilated.",

keywords = "EPR, Glasses, Irradiation, Mixed alkali effect, Raman",

author = "N. Ollier and B. Boizot and B. Reynard and D. Ghaleb and G. Petite",

year = "2004",

month = jun,

day = "1",

doi = "10.1016/j.nimb.2003.12.014",

language = "English",

volume = "218",

pages = "176--182",

journal = "Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms",

issn = "0168-583X",

publisher = "Elsevier B.V.",

number = "1-4",

note = "Proceedings of the Twelfth International Conference on Radiation ; Conference date: 31-08-2003 Through 05-09-2003",

}

β irradiation in borosilicate glasses: The role of the mixed alkali effect. / Ollier, N.; Boizot, B.; Reynard, B. et al.
Dans: Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms, Vol 218, Numéro 1-4, 01.06.2004, p. 176-182.

Résultats de recherche: Contribution à un journal › Article de conférence › Revue par des pairs

TY - JOUR

T1 - β irradiation in borosilicate glasses

T2 - Proceedings of the Twelfth International Conference on Radiation

AU - Ollier, N.

AU - Boizot, B.

AU - Reynard, B.

AU - Ghaleb, D.

AU - Petite, G.

PY - 2004/6/1

Y1 - 2004/6/1

N2 - Two series of mixed alkali borosilicate glasses have been studied (Na/K and Na/Li) in order to examine the mixed alkali effect influence on the structure evolution of β-irradiated glasses. In both glass series, paramagnetic defects concentration shows a non-linear variation with Na content. The defect nature is also affected and more particularly boron oxygen hole center versus oxygen hole center relative proportion. By Raman spectroscopy, we showed that polymerization increase and molecular oxygen production, linked to the alkali migration, were minimized for some irradiated glass compositions. Mixed alkali effect blocks structural changes under electron irradiation in Na/Li glasses while for Na/K glasses, structural evolutions are smaller than in pure alkali glasses but non-completely annihilated.

AB - Two series of mixed alkali borosilicate glasses have been studied (Na/K and Na/Li) in order to examine the mixed alkali effect influence on the structure evolution of β-irradiated glasses. In both glass series, paramagnetic defects concentration shows a non-linear variation with Na content. The defect nature is also affected and more particularly boron oxygen hole center versus oxygen hole center relative proportion. By Raman spectroscopy, we showed that polymerization increase and molecular oxygen production, linked to the alkali migration, were minimized for some irradiated glass compositions. Mixed alkali effect blocks structural changes under electron irradiation in Na/Li glasses while for Na/K glasses, structural evolutions are smaller than in pure alkali glasses but non-completely annihilated.

KW - EPR

KW - Glasses

KW - Irradiation

KW - Mixed alkali effect

KW - Raman

U2 - 10.1016/j.nimb.2003.12.014

DO - 10.1016/j.nimb.2003.12.014

M3 - Conference article

AN - SCOPUS:2342652924

SN - 0168-583X

VL - 218

SP - 176

EP - 182

JO - Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms

JF - Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms

IS - 1-4

Y2 - 31 August 2003 through 5 September 2003

ER -

β irradiation in borosilicate glasses: The role of the mixed alkali effect

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