(η5-halogenocyclohexadienyl)Mn(CO)3 complexes: Halogen substitution by arene derivatives

Damien Prim; Audrey Auffrant; François Rose-Munch; Eric Rose; Jacqueline Vaissermann

doi:10.1021/om000831d

(η⁵-halogenocyclohexadienyl)Mn(CO)₃ complexes: Halogen substitution by arene derivatives

Damien Prim
, Audrey Auffrant
, François Rose-Munch
, Eric Rose
, Jacqueline Vaissermann

CNRS
E.S.A 8007 du C.N.R.S

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

Unprecedented coupling reactions on (η⁵-chlorocyclohexadienyl)tricarbonyl manganese complexes with arenes create a new carbon-carbon bond on the conjugated system, keeping intact the η⁵-chlorocyclohexadienyl moiety; thus, the removal of the exo hydrogen bond of the sp³ CH₂ group yields efficiently new cationic (η⁶-arene) manganese complexes which cannot be prepared directly from the free arene.

langue originale	Anglais
Pages (de - à)	1901-1903
Nombre de pages	3
journal	Organometallics
Volume	20
Numéro de publication	10
Les DOIs	https://doi.org/10.1021/om000831d
état	Publié - 14 mai 2001

Accès au document

10.1021/om000831d

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title = "(η5-halogenocyclohexadienyl)Mn(CO)3 complexes: Halogen substitution by arene derivatives",

abstract = "Unprecedented coupling reactions on (η5-chlorocyclohexadienyl)tricarbonyl manganese complexes with arenes create a new carbon-carbon bond on the conjugated system, keeping intact the η5-chlorocyclohexadienyl moiety; thus, the removal of the exo hydrogen bond of the sp3 CH2 group yields efficiently new cationic (η6-arene) manganese complexes which cannot be prepared directly from the free arene.",

author = "Damien Prim and Audrey Auffrant and Fran{\c c}ois Rose-Munch and Eric Rose and Jacqueline Vaissermann",

year = "2001",

month = may,

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doi = "10.1021/om000831d",

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journal = "Organometallics",

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T2 - Halogen substitution by arene derivatives

AU - Prim, Damien

AU - Auffrant, Audrey

AU - Rose-Munch, François

AU - Rose, Eric

AU - Vaissermann, Jacqueline

PY - 2001/5/14

Y1 - 2001/5/14

N2 - Unprecedented coupling reactions on (η5-chlorocyclohexadienyl)tricarbonyl manganese complexes with arenes create a new carbon-carbon bond on the conjugated system, keeping intact the η5-chlorocyclohexadienyl moiety; thus, the removal of the exo hydrogen bond of the sp3 CH2 group yields efficiently new cationic (η6-arene) manganese complexes which cannot be prepared directly from the free arene.

AB - Unprecedented coupling reactions on (η5-chlorocyclohexadienyl)tricarbonyl manganese complexes with arenes create a new carbon-carbon bond on the conjugated system, keeping intact the η5-chlorocyclohexadienyl moiety; thus, the removal of the exo hydrogen bond of the sp3 CH2 group yields efficiently new cationic (η6-arene) manganese complexes which cannot be prepared directly from the free arene.

UR - https://www.scopus.com/pages/publications/0035858978

U2 - 10.1021/om000831d

DO - 10.1021/om000831d

M3 - Article

AN - SCOPUS:0035858978

SN - 0276-7333

VL - 20

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JO - Organometallics

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