A concise synthesis of an advanced Clerodin intermediate through a Vaultier tandem reaction

Jean Yves Lallemand; Yvan Six; Louis Ricard

doi:10.1002/1099-0690(20022)2002:3<503::AID-EJOC503>3.0.CO;2-6

A concise synthesis of an advanced Clerodin intermediate through a Vaultier tandem reaction

Jean Yves Lallemand
, Yvan Six
, Louis Ricard

Laboratoire de Synthèse Organique
CNRS
CNRS

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

A highly functionalised precursor of the antifeedant natural product Clerodin has been synthesised with good diastereo-control. Key steps include a three-component version of the Vaultier tandem sequence, and an oxidative decarboxylation with a simple experimental procedure.

langue originale	Anglais
Pages (de - à)	503-513
Nombre de pages	11
journal	European Journal of Organic Chemistry
Numéro de publication	3
Les DOIs	https://doi.org/10.1002/1099-0690(20022)2002:3<503::AID-EJOC503>3.0.CO;2-6
état	Publié - 1 janv. 2002

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10.1002/1099-0690(20022)2002:3<503::AID-EJOC503>3.0.CO;2-6

Contient cette citation

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title = "A concise synthesis of an advanced Clerodin intermediate through a Vaultier tandem reaction",

abstract = "A highly functionalised precursor of the antifeedant natural product Clerodin has been synthesised with good diastereo-control. Key steps include a three-component version of the Vaultier tandem sequence, and an oxidative decarboxylation with a simple experimental procedure.",

keywords = "Boron, Cycloadditions, Oxygenations, Terpenoids",

author = "Lallemand, \{Jean Yves\} and Yvan Six and Louis Ricard",

year = "2002",

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doi = "10.1002/1099-0690(20022)2002:3<503::AID-EJOC503>3.0.CO;2-6",

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journal = "European Journal of Organic Chemistry",

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AU - Lallemand, Jean Yves

AU - Six, Yvan

AU - Ricard, Louis

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N2 - A highly functionalised precursor of the antifeedant natural product Clerodin has been synthesised with good diastereo-control. Key steps include a three-component version of the Vaultier tandem sequence, and an oxidative decarboxylation with a simple experimental procedure.

AB - A highly functionalised precursor of the antifeedant natural product Clerodin has been synthesised with good diastereo-control. Key steps include a three-component version of the Vaultier tandem sequence, and an oxidative decarboxylation with a simple experimental procedure.

KW - Boron

KW - Cycloadditions

KW - Oxygenations

KW - Terpenoids

U2 - 10.1002/1099-0690(20022)2002:3<503::AID-EJOC503>3.0.CO;2-6

DO - 10.1002/1099-0690(20022)2002:3<503::AID-EJOC503>3.0.CO;2-6

M3 - Article

AN - SCOPUS:0036167019

SN - 1434-193X

SP - 503

EP - 513

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 3

ER -

A concise synthesis of an advanced Clerodin intermediate through a Vaultier tandem reaction

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