A cyclic divalent N(i) species isoelectronic to carbodiphosphoranes

Jiaxin Tian; Marie Cordier; Christophe Bour; Audrey Auffrant; Vincent Gandon

doi:10.1039/d2cc01637k

A cyclic divalent N(i) species isoelectronic to carbodiphosphoranes

Jiaxin Tian
, Marie Cordier
, Christophe Bour
, Audrey Auffrant
, Vincent Gandon

Institut de Chimie Moléculaire et des Matériaux d'Orsay
CNRS

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

The formation of a rare type of diphosphazenium cation is described. Its synthesis features a unique oxidative dealkylation of an iminophosphorane-phosphole by a silver(i) salt. DFT study of this compound reveals the low valent character of the N(i) center.

langue originale	Anglais
Pages (de - à)	5741-5744
Nombre de pages	4
journal	Chemical Communications
Volume	58
Numéro de publication	38
Les DOIs	https://doi.org/10.1039/d2cc01637k
état	Publié - 11 mai 2022
Modification externe	Oui

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10.1039/d2cc01637k

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title = "A cyclic divalent N(i) species isoelectronic to carbodiphosphoranes",

abstract = "The formation of a rare type of diphosphazenium cation is described. Its synthesis features a unique oxidative dealkylation of an iminophosphorane-phosphole by a silver(i) salt. DFT study of this compound reveals the low valent character of the N(i) center.",

author = "Jiaxin Tian and Marie Cordier and Christophe Bour and Audrey Auffrant and Vincent Gandon",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry, 2022",

year = "2022",

month = may,

day = "11",

doi = "10.1039/d2cc01637k",

language = "English",

volume = "58",

pages = "5741--5744",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - A cyclic divalent N(i) species isoelectronic to carbodiphosphoranes

AU - Tian, Jiaxin

AU - Cordier, Marie

AU - Bour, Christophe

AU - Auffrant, Audrey

AU - Gandon, Vincent

PY - 2022/5/11

Y1 - 2022/5/11

N2 - The formation of a rare type of diphosphazenium cation is described. Its synthesis features a unique oxidative dealkylation of an iminophosphorane-phosphole by a silver(i) salt. DFT study of this compound reveals the low valent character of the N(i) center.

AB - The formation of a rare type of diphosphazenium cation is described. Its synthesis features a unique oxidative dealkylation of an iminophosphorane-phosphole by a silver(i) salt. DFT study of this compound reveals the low valent character of the N(i) center.

U2 - 10.1039/d2cc01637k

DO - 10.1039/d2cc01637k

M3 - Article

C2 - 35466973

AN - SCOPUS:85130001449

SN - 1359-7345

VL - 58

SP - 5741

EP - 5744

JO - Chemical Communications

JF - Chemical Communications

IS - 38

ER -

A cyclic divalent N(i) species isoelectronic to carbodiphosphoranes

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