A direct approach to α-trifluoromethylamines

Fabien Gagosz; Samir Z. Zard

doi:10.1021/ol034812m

A direct approach to α-trifluoromethylamines

Fabien Gagosz
, Samir Z. Zard

Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

62 Citations (Scopus)

Résumé

(Matrix presented) S-[1-(N-Acetylamino)-2,2,2-trifluoroethyl]-O-ethyl dithiocarbonate (6), a readily available xanthate, adds efficiently to various functionalized olefins to give the corresponding adducts 8 via a radical chain reaction initiated by a small amount of lauroyl peroxide.

langue originale	Anglais
Pages (de - à)	2655-2657
Nombre de pages	3
journal	Organic Letters
Volume	5
Numéro de publication	15
Les DOIs	https://doi.org/10.1021/ol034812m
état	Publié - 24 juil. 2003
Modification externe	Oui

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10.1021/ol034812m

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@article{b27c85a62d0d4bfcaa00fe54f1403308,

title = "A direct approach to α-trifluoromethylamines",

abstract = "(Matrix presented) S-[1-(N-Acetylamino)-2,2,2-trifluoroethyl]-O-ethyl dithiocarbonate (6), a readily available xanthate, adds efficiently to various functionalized olefins to give the corresponding adducts 8 via a radical chain reaction initiated by a small amount of lauroyl peroxide.",

author = "Fabien Gagosz and Zard, \{Samir Z.\}",

year = "2003",

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doi = "10.1021/ol034812m",

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T1 - A direct approach to α-trifluoromethylamines

AU - Gagosz, Fabien

AU - Zard, Samir Z.

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N2 - (Matrix presented) S-[1-(N-Acetylamino)-2,2,2-trifluoroethyl]-O-ethyl dithiocarbonate (6), a readily available xanthate, adds efficiently to various functionalized olefins to give the corresponding adducts 8 via a radical chain reaction initiated by a small amount of lauroyl peroxide.

AB - (Matrix presented) S-[1-(N-Acetylamino)-2,2,2-trifluoroethyl]-O-ethyl dithiocarbonate (6), a readily available xanthate, adds efficiently to various functionalized olefins to give the corresponding adducts 8 via a radical chain reaction initiated by a small amount of lauroyl peroxide.

U2 - 10.1021/ol034812m

DO - 10.1021/ol034812m

M3 - Article

AN - SCOPUS:0141631561

SN - 1523-7060

VL - 5

SP - 2655

EP - 2657

JO - Organic Letters

JF - Organic Letters

IS - 15

ER -

A direct approach to α-trifluoromethylamines

Résumé

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