A Direct Approach to Enantiopure Propionate Derivatives from Ethyl Lactate

David Clemente-Tejeda; Juan Carlos Ortiz Lara; Samir Z. Zard

doi:10.1055/s-0035-1562449

A Direct Approach to Enantiopure Propionate Derivatives from Ethyl Lactate

David Clemente-Tejeda
, Juan Carlos Ortiz Lara
, Samir Z. Zard

Laboratoire de Synthèse Organique
Sintenovo S.A de C.v.

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

The S-propargyl xanthate derived from ethyl (S)-lactate reacts upon heating with various acidic substances to give the propionate transfer product in high yield and with complete inversion of configuration.

langue originale	Anglais
Numéro d'article	ss-2016-c0375-op
Pages (de - à)	3393-3399
Nombre de pages	7
journal	Synthesis
Volume	48
Numéro de publication	19
Les DOIs	https://doi.org/10.1055/s-0035-1562449
état	Publié - 4 oct. 2016
Modification externe	Oui

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10.1055/s-0035-1562449

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@article{1454ee6a79c64b60ba50e79975d3b94d,

title = "A Direct Approach to Enantiopure Propionate Derivatives from Ethyl Lactate",

abstract = "The S-propargyl xanthate derived from ethyl (S)-lactate reacts upon heating with various acidic substances to give the propionate transfer product in high yield and with complete inversion of configuration.",

keywords = "S -propargyl xanthate, esters, inversion, propionates, sigmatropic rearrangement",

author = "David Clemente-Tejeda and Lara, \{Juan Carlos Ortiz\} and Zard, \{Samir Z.\}",

note = "Publisher Copyright: {\textcopyright} Georg Thieme Verlag Stuttgart New York.",

year = "2016",

month = oct,

day = "4",

doi = "10.1055/s-0035-1562449",

language = "English",

volume = "48",

pages = "3393--3399",

journal = "Synthesis",

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T1 - A Direct Approach to Enantiopure Propionate Derivatives from Ethyl Lactate

AU - Clemente-Tejeda, David

AU - Lara, Juan Carlos Ortiz

AU - Zard, Samir Z.

N1 - Publisher Copyright: © Georg Thieme Verlag Stuttgart New York.

PY - 2016/10/4

Y1 - 2016/10/4

N2 - The S-propargyl xanthate derived from ethyl (S)-lactate reacts upon heating with various acidic substances to give the propionate transfer product in high yield and with complete inversion of configuration.

AB - The S-propargyl xanthate derived from ethyl (S)-lactate reacts upon heating with various acidic substances to give the propionate transfer product in high yield and with complete inversion of configuration.

KW - S -propargyl xanthate

KW - esters

KW - inversion

KW - propionates

KW - sigmatropic rearrangement

U2 - 10.1055/s-0035-1562449

DO - 10.1055/s-0035-1562449

M3 - Article

AN - SCOPUS:84978493443

SN - 0039-7881

VL - 48

SP - 3393

EP - 3399

JO - Synthesis

JF - Synthesis

IS - 19

M1 - ss-2016-c0375-op

ER -

A Direct Approach to Enantiopure Propionate Derivatives from Ethyl Lactate

Résumé

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