A Direct Xanthate-Based Route to γ-Thiolactones

Raphaël Simonet-Davin; Samir Z. Zard

doi:10.1055/s-0036-1590987

A Direct Xanthate-Based Route to γ-Thiolactones

Raphaël Simonet-Davin
, Samir Z. Zard

Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

6 Citations (Scopus)

Résumé

The first examples of direct synthesis of γ-thiolactones by addition of a thiolactone-based radical are described. Mono- and bis-γ-thiolactones can be obtained by a dilauroyl peroxide initiated addition of thiolactone xanthate to various alkenes and α,ω-dienes. The process is modular and exhibits a high functional group tolerance.

langue originale	Anglais
Pages (de - à)	815-819
Nombre de pages	5
journal	Synlett
Volume	29
Numéro de publication	6
Les DOIs	https://doi.org/10.1055/s-0036-1590987
état	Publié - 3 avr. 2018
Modification externe	Oui

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10.1055/s-0036-1590987

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title = "A Direct Xanthate-Based Route to γ-Thiolactones",

abstract = "The first examples of direct synthesis of γ-thiolactones by addition of a thiolactone-based radical are described. Mono- and bis-γ-thiolactones can be obtained by a dilauroyl peroxide initiated addition of thiolactone xanthate to various alkenes and α,ω-dienes. The process is modular and exhibits a high functional group tolerance.",

keywords = "alkenes, polymers, radical addition, thiolactones, xanthates",

author = "Rapha{\"e}l Simonet-Davin and Zard, \{Samir Z.\}",

note = "Publisher Copyright: {\textcopyright} Georg Thieme Verlag Stuttgart New York.",

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AU - Zard, Samir Z.

N1 - Publisher Copyright: © Georg Thieme Verlag Stuttgart New York.

PY - 2018/4/3

Y1 - 2018/4/3

N2 - The first examples of direct synthesis of γ-thiolactones by addition of a thiolactone-based radical are described. Mono- and bis-γ-thiolactones can be obtained by a dilauroyl peroxide initiated addition of thiolactone xanthate to various alkenes and α,ω-dienes. The process is modular and exhibits a high functional group tolerance.

AB - The first examples of direct synthesis of γ-thiolactones by addition of a thiolactone-based radical are described. Mono- and bis-γ-thiolactones can be obtained by a dilauroyl peroxide initiated addition of thiolactone xanthate to various alkenes and α,ω-dienes. The process is modular and exhibits a high functional group tolerance.

KW - alkenes

KW - polymers

KW - radical addition

KW - thiolactones

KW - xanthates

U2 - 10.1055/s-0036-1590987

DO - 10.1055/s-0036-1590987

M3 - Article

AN - SCOPUS:85040087431

SN - 0936-5214

VL - 29

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JO - Synlett

JF - Synlett

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A Direct Xanthate-Based Route to γ-Thiolactones

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