A highly stereoselective, modular route to (E)-vinylsulfones and to (Z)- and (E)-alkenes

Marie Gabrielle Braun; Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.1021/ja207944c

A highly stereoselective, modular route to (E)-vinylsulfones and to (Z)- and (E)-alkenes

Marie Gabrielle Braun
, Béatrice Quiclet-Sire
, Samir Z. Zard

Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

43 Citations (Scopus)

Résumé

A recently discovered radical fragmentation of 2-fluoro-6-pyridinoxy derivatives allows a new highly stereoselective and convergent route to (E)-vinylsulfones from allylic alcohols. Reductive desulfonylation or nickel-catalyzed couplings furnish di- and trisubstituted (E)- and (Z)-alkenes.

langue originale	Anglais
Pages (de - à)	15954-15957
Nombre de pages	4
journal	Journal of the American Chemical Society
Volume	133
Numéro de publication	40
Les DOIs	https://doi.org/10.1021/ja207944c
état	Publié - 12 oct. 2011
Modification externe	Oui

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10.1021/ja207944c

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title = "A highly stereoselective, modular route to (E)-vinylsulfones and to (Z)- and (E)-alkenes",

abstract = "A recently discovered radical fragmentation of 2-fluoro-6-pyridinoxy derivatives allows a new highly stereoselective and convergent route to (E)-vinylsulfones from allylic alcohols. Reductive desulfonylation or nickel-catalyzed couplings furnish di- and trisubstituted (E)- and (Z)-alkenes.",

author = "Braun, \{Marie Gabrielle\} and B{\'e}atrice Quiclet-Sire and Zard, \{Samir Z.\}",

year = "2011",

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T1 - A highly stereoselective, modular route to (E)-vinylsulfones and to (Z)- and (E)-alkenes

AU - Braun, Marie Gabrielle

AU - Quiclet-Sire, Béatrice

AU - Zard, Samir Z.

PY - 2011/10/12

Y1 - 2011/10/12

N2 - A recently discovered radical fragmentation of 2-fluoro-6-pyridinoxy derivatives allows a new highly stereoselective and convergent route to (E)-vinylsulfones from allylic alcohols. Reductive desulfonylation or nickel-catalyzed couplings furnish di- and trisubstituted (E)- and (Z)-alkenes.

AB - A recently discovered radical fragmentation of 2-fluoro-6-pyridinoxy derivatives allows a new highly stereoselective and convergent route to (E)-vinylsulfones from allylic alcohols. Reductive desulfonylation or nickel-catalyzed couplings furnish di- and trisubstituted (E)- and (Z)-alkenes.

U2 - 10.1021/ja207944c

DO - 10.1021/ja207944c

M3 - Article

AN - SCOPUS:80053461951

SN - 0002-7863

VL - 133

SP - 15954

EP - 15957

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 40

ER -

A highly stereoselective, modular route to (E)-vinylsulfones and to (Z)- and (E)-alkenes

Résumé

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