A mild exchange reaction of xanthates with bromine

Francis Barbier; François Pautrat; Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.1055/s-2002-25343

A mild exchange reaction of xanthates with bromine

Francis Barbier
, François Pautrat
, Béatrice Quiclet-Sire
, Samir Z. Zard

Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

30 Citations (Scopus)

Résumé

Secondary S-alkyl-O-ethyl (or O-neopentyl) xanthates can be converted into the corresponding bromides by heating with ethyl 2-bromo-2-methylpropionate and cumyl peroxide in refluxing chlorobenzene; this transformation can be coupled to a xanthate transfer radical addition to an olefin.

langue originale	Anglais
Pages (de - à)	811-813
Nombre de pages	3
journal	Synlett
Numéro de publication	5
Les DOIs	https://doi.org/10.1055/s-2002-25343
état	Publié - 1 janv. 2002
Modification externe	Oui

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10.1055/s-2002-25343

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title = "A mild exchange reaction of xanthates with bromine",

abstract = "Secondary S-alkyl-O-ethyl (or O-neopentyl) xanthates can be converted into the corresponding bromides by heating with ethyl 2-bromo-2-methylpropionate and cumyl peroxide in refluxing chlorobenzene; this transformation can be coupled to a xanthate transfer radical addition to an olefin.",

keywords = "Bromine atom transfer, Lactones, Radical reactions, Xanthates",

author = "Francis Barbier and Fran{\c c}ois Pautrat and B{\'e}atrice Quiclet-Sire and Zard, \{Samir Z.\}",

year = "2002",

month = jan,

day = "1",

doi = "10.1055/s-2002-25343",

language = "English",

pages = "811--813",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "5",

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TY - JOUR

T1 - A mild exchange reaction of xanthates with bromine

AU - Barbier, Francis

AU - Pautrat, François

AU - Quiclet-Sire, Béatrice

AU - Zard, Samir Z.

PY - 2002/1/1

Y1 - 2002/1/1

N2 - Secondary S-alkyl-O-ethyl (or O-neopentyl) xanthates can be converted into the corresponding bromides by heating with ethyl 2-bromo-2-methylpropionate and cumyl peroxide in refluxing chlorobenzene; this transformation can be coupled to a xanthate transfer radical addition to an olefin.

AB - Secondary S-alkyl-O-ethyl (or O-neopentyl) xanthates can be converted into the corresponding bromides by heating with ethyl 2-bromo-2-methylpropionate and cumyl peroxide in refluxing chlorobenzene; this transformation can be coupled to a xanthate transfer radical addition to an olefin.

KW - Bromine atom transfer

KW - Lactones

KW - Radical reactions

KW - Xanthates

U2 - 10.1055/s-2002-25343

DO - 10.1055/s-2002-25343

M3 - Article

AN - SCOPUS:0036256048

SN - 0936-5214

SP - 811

EP - 813

JO - Synlett

JF - Synlett

IS - 5

ER -

A mild exchange reaction of xanthates with bromine

Résumé

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