A new radical based synthesis of lactams and indolones from dithiocarbonates (xanthates)

Jonathan Axon; Laurent Boiteau; Jean Boivin; Judith E. Forbes; Samir Z. Zard

doi:10.1016/0040-4039(94)88328-9

A new radical based synthesis of lactams and indolones from dithiocarbonates (xanthates)

Jonathan Axon
, Laurent Boiteau
, Jean Boivin
, Judith E. Forbes
, Samir Z. Zard

Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

72 Citations (Scopus)

Résumé

N,N-disubstituted a-(xanthyl)-acetamides with an olefin on one of the substituents undergo cyclisation to a lactam by a radical chain reaction involving transfer of the xanthate group; anilides lead to the corresponding indolones.

langue originale	Anglais
Pages (de - à)	1719-1722
Nombre de pages	4
journal	Tetrahedron Letters
Volume	35
Numéro de publication	11
Les DOIs	https://doi.org/10.1016/0040-4039(94)88328-9
état	Publié - 14 mars 1994
Modification externe	Oui

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10.1016/0040-4039(94)88328-9

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title = "A new radical based synthesis of lactams and indolones from dithiocarbonates (xanthates)",

abstract = "N,N-disubstituted a-(xanthyl)-acetamides with an olefin on one of the substituents undergo cyclisation to a lactam by a radical chain reaction involving transfer of the xanthate group; anilides lead to the corresponding indolones.",

author = "Jonathan Axon and Laurent Boiteau and Jean Boivin and Forbes, \{Judith E.\} and Zard, \{Samir Z.\}",

year = "1994",

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T1 - A new radical based synthesis of lactams and indolones from dithiocarbonates (xanthates)

AU - Axon, Jonathan

AU - Boiteau, Laurent

AU - Boivin, Jean

AU - Forbes, Judith E.

AU - Zard, Samir Z.

PY - 1994/3/14

Y1 - 1994/3/14

N2 - N,N-disubstituted a-(xanthyl)-acetamides with an olefin on one of the substituents undergo cyclisation to a lactam by a radical chain reaction involving transfer of the xanthate group; anilides lead to the corresponding indolones.

AB - N,N-disubstituted a-(xanthyl)-acetamides with an olefin on one of the substituents undergo cyclisation to a lactam by a radical chain reaction involving transfer of the xanthate group; anilides lead to the corresponding indolones.

U2 - 10.1016/0040-4039(94)88328-9

DO - 10.1016/0040-4039(94)88328-9

M3 - Article

AN - SCOPUS:0028314798

SN - 0040-4039

VL - 35

SP - 1719

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 11

ER -

A new radical based synthesis of lactams and indolones from dithiocarbonates (xanthates)

Résumé

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