A new radical vinylation reaction of iodides and dithiocarbonates

Frédérique Bertrand; Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.1002/(SICI)1521-3773(19990712)38:13/14<1943::AID-ANIE1943>3.0.CO;2-R

A new radical vinylation reaction of iodides and dithiocarbonates

Frédérique Bertrand
, Béatrice Quiclet-Sire
, Samir Z. Zard

Institut de Chimie des Substances Naturelles
Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

Heavy metals can be avoided with a new radical equivalent of the Heck reaction for aliphatic derivatives in which iodide and dithiocarbonate substituents are replaced by substituted vinyl groups [Eq.(1)]. The reaction enables the introduction of vinyl fragments into a variety of functionalized substrates.

langue originale	Anglais
Pages (de - à)	1943-1946
Nombre de pages	4
journal	Angewandte Chemie - International Edition
Volume	38
Numéro de publication	13-14
Les DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990712)38:13/14<1943::AID-ANIE1943>3.0.CO;2-R
état	Publié - 12 juil. 1999
Modification externe	Oui

Accès au document

10.1002/(SICI)1521-3773(19990712)38:13/14<1943::AID-ANIE1943>3.0.CO;2-R

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title = "A new radical vinylation reaction of iodides and dithiocarbonates",

abstract = "Heavy metals can be avoided with a new radical equivalent of the Heck reaction for aliphatic derivatives in which iodide and dithiocarbonate substituents are replaced by substituted vinyl groups [Eq.(1)]. The reaction enables the introduction of vinyl fragments into a variety of functionalized substrates.",

keywords = "Alkenes, Allylation, C-C coupling, Radical reactions, Vinyl sulfones",

author = "Fr{\'e}d{\'e}rique Bertrand and B{\'e}atrice Quiclet-Sire and Zard, \{Samir Z.\}",

year = "1999",

month = jul,

day = "12",

doi = "10.1002/(SICI)1521-3773(19990712)38:13/14<1943::AID-ANIE1943>3.0.CO;2-R",

language = "English",

volume = "38",

pages = "1943--1946",

journal = "Angewandte Chemie - International Edition",

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T1 - A new radical vinylation reaction of iodides and dithiocarbonates

AU - Bertrand, Frédérique

AU - Quiclet-Sire, Béatrice

AU - Zard, Samir Z.

PY - 1999/7/12

Y1 - 1999/7/12

N2 - Heavy metals can be avoided with a new radical equivalent of the Heck reaction for aliphatic derivatives in which iodide and dithiocarbonate substituents are replaced by substituted vinyl groups [Eq.(1)]. The reaction enables the introduction of vinyl fragments into a variety of functionalized substrates.

AB - Heavy metals can be avoided with a new radical equivalent of the Heck reaction for aliphatic derivatives in which iodide and dithiocarbonate substituents are replaced by substituted vinyl groups [Eq.(1)]. The reaction enables the introduction of vinyl fragments into a variety of functionalized substrates.

KW - Alkenes

KW - Allylation

KW - C-C coupling

KW - Radical reactions

KW - Vinyl sulfones

UR - https://www.scopus.com/pages/publications/0033549583

U2 - 10.1002/(SICI)1521-3773(19990712)38:13/14<1943::AID-ANIE1943>3.0.CO;2-R

DO - 10.1002/(SICI)1521-3773(19990712)38:13/14<1943::AID-ANIE1943>3.0.CO;2-R

M3 - Article

AN - SCOPUS:0033549583

SN - 1433-7851

VL - 38

SP - 1943

EP - 1946

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 13-14

ER -

A new radical vinylation reaction of iodides and dithiocarbonates

Résumé

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