A new synthesis of substituted dienes by reductive elimination of allylic nitro derivatives

Bernard Barlaam; Jean Boivin; Samir Z. Zard

doi:10.1016/S0040-4039(00)77482-X

A new synthesis of substituted dienes by reductive elimination of allylic nitro derivatives

Bernard Barlaam
, Jean Boivin
, Samir Z. Zard

Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

13 Citations (Scopus)

Résumé

Tertiary allylic nitro compounds, bearing an acetate or a mesylate in β position smoothly undergo a reductive elimination to give conjugated 1,3 dienes when treated with chromous acetate/ 2,2′-dipyridyl in DMF at 110-120°C.

langue originale	Anglais
Pages (de - à)	1023-1026
Nombre de pages	4
journal	Tetrahedron Letters
Volume	34
Numéro de publication	6
Les DOIs	https://doi.org/10.1016/S0040-4039(00)77482-X
état	Publié - 5 févr. 1993
Modification externe	Oui

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10.1016/S0040-4039(00)77482-X

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@article{efd4d73be05c4bffa9e31996fdc30789,

title = "A new synthesis of substituted dienes by reductive elimination of allylic nitro derivatives",

abstract = "Tertiary allylic nitro compounds, bearing an acetate or a mesylate in β position smoothly undergo a reductive elimination to give conjugated 1,3 dienes when treated with chromous acetate/ 2,2′-dipyridyl in DMF at 110-120°C.",

keywords = "Allylic nitro compounds, chromous acetate., dienes, reduction",

author = "Bernard Barlaam and Jean Boivin and Zard, \{Samir Z.\}",

year = "1993",

month = feb,

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doi = "10.1016/S0040-4039(00)77482-X",

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T1 - A new synthesis of substituted dienes by reductive elimination of allylic nitro derivatives

AU - Barlaam, Bernard

AU - Boivin, Jean

AU - Zard, Samir Z.

PY - 1993/2/5

Y1 - 1993/2/5

N2 - Tertiary allylic nitro compounds, bearing an acetate or a mesylate in β position smoothly undergo a reductive elimination to give conjugated 1,3 dienes when treated with chromous acetate/ 2,2′-dipyridyl in DMF at 110-120°C.

AB - Tertiary allylic nitro compounds, bearing an acetate or a mesylate in β position smoothly undergo a reductive elimination to give conjugated 1,3 dienes when treated with chromous acetate/ 2,2′-dipyridyl in DMF at 110-120°C.

KW - Allylic nitro compounds

KW - chromous acetate.

KW - dienes

KW - reduction

U2 - 10.1016/S0040-4039(00)77482-X

DO - 10.1016/S0040-4039(00)77482-X

M3 - Article

AN - SCOPUS:0027466697

SN - 0040-4039

VL - 34

SP - 1023

EP - 1026

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 6

ER -

A new synthesis of substituted dienes by reductive elimination of allylic nitro derivatives

Résumé

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