A novel {FeI-FeII-FeII-FeI} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution

Cédric Tard; Xiaoming Liu; David L. Hughes; Christopher J. Pickett

doi:10.1039/b411559g

A novel {Fe^I-Fe^II-Fe^II-Fe^I} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution

Cédric Tard
, Xiaoming Liu
, David L. Hughes
, Christopher J. Pickett

John Innes Centre
Department of Biological Chemistry

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

65 Citations (Scopus)

Résumé

A novel tetra-iron thiolate carbonyl assembly is described in which two dithiolate tetracarbonyl di-iron centres with a 'butterfly' configuration of the {2Fe3S}-cores are fused by two bridging thiolates which form a central planar 2Fe2S unit and comprise the first example of a chain of four metal-metal bonded iron atoms supported by a bridging sulfur framework; the assembly electrocatalyses hydrogen evolution.

langue originale	Anglais
Pages (de - à)	133-135
Nombre de pages	3
journal	Chemical Communications
Numéro de publication	1
Les DOIs	https://doi.org/10.1039/b411559g
état	Publié - 7 janv. 2005
Modification externe	Oui

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10.1039/b411559g

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title = "A novel \{FeI-FeII-FeII-FeI\} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution",

abstract = "A novel tetra-iron thiolate carbonyl assembly is described in which two dithiolate tetracarbonyl di-iron centres with a 'butterfly' configuration of the \{2Fe3S\}-cores are fused by two bridging thiolates which form a central planar 2Fe2S unit and comprise the first example of a chain of four metal-metal bonded iron atoms supported by a bridging sulfur framework; the assembly electrocatalyses hydrogen evolution.",

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year = "2005",

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pages = "133--135",

journal = "Chemical Communications",

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T1 - A novel {FeI-FeII-FeII-FeI} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution

AU - Tard, Cédric

AU - Liu, Xiaoming

AU - Hughes, David L.

AU - Pickett, Christopher J.

PY - 2005/1/7

Y1 - 2005/1/7

N2 - A novel tetra-iron thiolate carbonyl assembly is described in which two dithiolate tetracarbonyl di-iron centres with a 'butterfly' configuration of the {2Fe3S}-cores are fused by two bridging thiolates which form a central planar 2Fe2S unit and comprise the first example of a chain of four metal-metal bonded iron atoms supported by a bridging sulfur framework; the assembly electrocatalyses hydrogen evolution.

AB - A novel tetra-iron thiolate carbonyl assembly is described in which two dithiolate tetracarbonyl di-iron centres with a 'butterfly' configuration of the {2Fe3S}-cores are fused by two bridging thiolates which form a central planar 2Fe2S unit and comprise the first example of a chain of four metal-metal bonded iron atoms supported by a bridging sulfur framework; the assembly electrocatalyses hydrogen evolution.

U2 - 10.1039/b411559g

DO - 10.1039/b411559g

M3 - Article

AN - SCOPUS:12744273184

SN - 1359-7345

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EP - 135

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

A novel {FeI-FeII-FeII-FeI} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution

Résumé

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Contient cette citation

A novel {Fe^I-Fe^II-Fe^II-Fe^I} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution