A short formal total synthesis of (±)-hirsutic acid

Guillaume Revol; Christian Fuchs; Samir Z. Zard

doi:10.1139/v2012-037

A short formal total synthesis of (±)-hirsutic acid

Guillaume Revol
, Christian Fuchs
, Samir Z. Zard

Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

9 Citations (Scopus)

Résumé

A short formal total synthesis of (±)-hirsutic acid is described using a Claisen rearrangement and a radical cascade as the key steps. The radical sequence involves an intermolecular addition of a radical derived from a xanthate followed by a cyclization and transfer of the xanthate group.

langue originale	Anglais
Pages (de - à)	927-931
Nombre de pages	5
journal	Canadian Journal of Chemistry
Volume	90
Numéro de publication	11
Les DOIs	https://doi.org/10.1139/v2012-037
état	Publié - 30 nov. 2012
Modification externe	Oui

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10.1139/v2012-037

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@article{8a4d65b747fa40799015935a93a4286d,

title = "A short formal total synthesis of (±)-hirsutic acid",

abstract = "A short formal total synthesis of (±)-hirsutic acid is described using a Claisen rearrangement and a radical cascade as the key steps. The radical sequence involves an intermolecular addition of a radical derived from a xanthate followed by a cyclization and transfer of the xanthate group.",

keywords = "Claisen rearrangement, Complicatic acid, Hirsutic acid, Radical cyclization, Triquinanes, Xanthates",

author = "Guillaume Revol and Christian Fuchs and Zard, \{Samir Z.\}",

year = "2012",

month = nov,

day = "30",

doi = "10.1139/v2012-037",

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volume = "90",

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T1 - A short formal total synthesis of (±)-hirsutic acid

AU - Revol, Guillaume

AU - Fuchs, Christian

AU - Zard, Samir Z.

PY - 2012/11/30

Y1 - 2012/11/30

N2 - A short formal total synthesis of (±)-hirsutic acid is described using a Claisen rearrangement and a radical cascade as the key steps. The radical sequence involves an intermolecular addition of a radical derived from a xanthate followed by a cyclization and transfer of the xanthate group.

AB - A short formal total synthesis of (±)-hirsutic acid is described using a Claisen rearrangement and a radical cascade as the key steps. The radical sequence involves an intermolecular addition of a radical derived from a xanthate followed by a cyclization and transfer of the xanthate group.

KW - Claisen rearrangement

KW - Complicatic acid

KW - Hirsutic acid

KW - Radical cyclization

KW - Triquinanes

KW - Xanthates

U2 - 10.1139/v2012-037

DO - 10.1139/v2012-037

M3 - Article

AN - SCOPUS:84870916637

SN - 0008-4042

VL - 90

SP - 927

EP - 931

JO - Canadian Journal of Chemistry

JF - Canadian Journal of Chemistry

IS - 11

ER -

A short formal total synthesis of (±)-hirsutic acid

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