A thermodynamic limit of the melting/freezing processes of water under strongly hydrophobic nanoscopic confinement

Johnny Deschamps; Fabrice Audonnet; Nancy Brodie-Linder; Markus Schoeffel; Christiane Alba-Simionesco

doi:10.1039/b920816j

A thermodynamic limit of the melting/freezing processes of water under strongly hydrophobic nanoscopic confinement

Johnny Deschamps
, Fabrice Audonnet
, Nancy Brodie-Linder
, Markus Schoeffel
, Christiane Alba-Simionesco

Université Paris-Sud 11
Unité Chimie et Procédés
Institut Pierre Simon Laplace, CNRS and CEA
CY Cergy Paris Université

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

We studied liquid water confined within nanopores which present a high level of hydrophobicity thanks to a new method of synthesis. We found that the liquid state persists down to temperatures much lower than in the bulk and in hydrophilic materials of comparable sizes, allowing us to define a thermodynamic limit for the melting/crystallization of water.

langue originale	Anglais
Pages (de - à)	1440-1443
Nombre de pages	4
journal	Physical Chemistry Chemical Physics
Volume	12
Numéro de publication	7
Les DOIs	https://doi.org/10.1039/b920816j
état	Publié - 3 févr. 2010
Modification externe	Oui

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10.1039/b920816j

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abstract = "We studied liquid water confined within nanopores which present a high level of hydrophobicity thanks to a new method of synthesis. We found that the liquid state persists down to temperatures much lower than in the bulk and in hydrophilic materials of comparable sizes, allowing us to define a thermodynamic limit for the melting/crystallization of water.",

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AU - Deschamps, Johnny

AU - Audonnet, Fabrice

AU - Brodie-Linder, Nancy

AU - Schoeffel, Markus

AU - Alba-Simionesco, Christiane

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AB - We studied liquid water confined within nanopores which present a high level of hydrophobicity thanks to a new method of synthesis. We found that the liquid state persists down to temperatures much lower than in the bulk and in hydrophilic materials of comparable sizes, allowing us to define a thermodynamic limit for the melting/crystallization of water.

UR - https://www.scopus.com/pages/publications/76249109193

U2 - 10.1039/b920816j

DO - 10.1039/b920816j

M3 - Article

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JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

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A thermodynamic limit of the melting/freezing processes of water under strongly hydrophobic nanoscopic confinement

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