A xanthate transfer radical process for the introduction of the Trifluoromethyl group

Frédérique Bertrand; Virginie Pevere; Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.1021/ol0156446

A xanthate transfer radical process for the introduction of the Trifluoromethyl group

Frédérique Bertrand
, Virginie Pevere
, Béatrice Quiclet-Sire
, Samir Z. Zard

Institut de Chimie des Substances Naturelles
Rhodia Recherches

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

66 Citations (Scopus)

Résumé

(matrix presented) S-Trifluoromethyl xanthates efficiently add to unactivated alkenes by a radical mechanism to give adducts with a trifluoromethyl group at the least hindered terminus of the olefin.

langue originale	Anglais
Pages (de - à)	1069-1071
Nombre de pages	3
journal	Organic Letters
Volume	3
Numéro de publication	7
Les DOIs	https://doi.org/10.1021/ol0156446
état	Publié - 5 avr. 2001

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10.1021/ol0156446

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@article{b35147b3a52042b0901b123e23f6d800,

title = "A xanthate transfer radical process for the introduction of the Trifluoromethyl group",

abstract = "(matrix presented) S-Trifluoromethyl xanthates efficiently add to unactivated alkenes by a radical mechanism to give adducts with a trifluoromethyl group at the least hindered terminus of the olefin.",

author = "Fr{\'e}d{\'e}rique Bertrand and Virginie Pevere and B{\'e}atrice Quiclet-Sire and Zard, \{Samir Z.\}",

year = "2001",

month = apr,

day = "5",

doi = "10.1021/ol0156446",

language = "English",

volume = "3",

pages = "1069--1071",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "7",

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TY - JOUR

T1 - A xanthate transfer radical process for the introduction of the Trifluoromethyl group

AU - Bertrand, Frédérique

AU - Pevere, Virginie

AU - Quiclet-Sire, Béatrice

AU - Zard, Samir Z.

PY - 2001/4/5

Y1 - 2001/4/5

N2 - (matrix presented) S-Trifluoromethyl xanthates efficiently add to unactivated alkenes by a radical mechanism to give adducts with a trifluoromethyl group at the least hindered terminus of the olefin.

AB - (matrix presented) S-Trifluoromethyl xanthates efficiently add to unactivated alkenes by a radical mechanism to give adducts with a trifluoromethyl group at the least hindered terminus of the olefin.

U2 - 10.1021/ol0156446

DO - 10.1021/ol0156446

M3 - Article

AN - SCOPUS:0001477881

SN - 1523-7060

VL - 3

SP - 1069

EP - 1071

JO - Organic Letters

JF - Organic Letters

IS - 7

ER -

A xanthate transfer radical process for the introduction of the Trifluoromethyl group

Résumé

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