Allylic alcohols as radical allylating agents. An overall olefination of aldehydes and ketones

Nicolas Charrier; Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.1021/ja802899m

Allylic alcohols as radical allylating agents. An overall olefination of aldehydes and ketones

Nicolas Charrier
, Béatrice Quiclet-Sire
, Samir Z. Zard

Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

41 Citations (Scopus)

Résumé

2-Fluoropyridyl derivatives of allylic alcohols react with xanthates in the presence of lauroyl peroxide to give alkenes, often with high stereoselectivity. If the allylic alcohols are themselves derived from aldehydes or ketones, the overall process becomes a synthetic equivalent of the classical Wittig and related olefination reactions.

langue originale	Anglais
Pages (de - à)	8898-8899
Nombre de pages	2
journal	Journal of the American Chemical Society
Volume	130
Numéro de publication	28
Les DOIs	https://doi.org/10.1021/ja802899m
état	Publié - 16 juil. 2008
Modification externe	Oui

Accès au document

10.1021/ja802899m

Contient cette citation

@article{68b5a83f5e3d45a384922d243fd9ecb6,

title = "Allylic alcohols as radical allylating agents. An overall olefination of aldehydes and ketones",

abstract = "2-Fluoropyridyl derivatives of allylic alcohols react with xanthates in the presence of lauroyl peroxide to give alkenes, often with high stereoselectivity. If the allylic alcohols are themselves derived from aldehydes or ketones, the overall process becomes a synthetic equivalent of the classical Wittig and related olefination reactions.",

author = "Nicolas Charrier and B{\'e}atrice Quiclet-Sire and Zard, \{Samir Z.\}",

year = "2008",

month = jul,

day = "16",

doi = "10.1021/ja802899m",

language = "English",

volume = "130",

pages = "8898--8899",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "28",

}

TY - JOUR

T1 - Allylic alcohols as radical allylating agents. An overall olefination of aldehydes and ketones

AU - Charrier, Nicolas

AU - Quiclet-Sire, Béatrice

AU - Zard, Samir Z.

PY - 2008/7/16

Y1 - 2008/7/16

N2 - 2-Fluoropyridyl derivatives of allylic alcohols react with xanthates in the presence of lauroyl peroxide to give alkenes, often with high stereoselectivity. If the allylic alcohols are themselves derived from aldehydes or ketones, the overall process becomes a synthetic equivalent of the classical Wittig and related olefination reactions.

AB - 2-Fluoropyridyl derivatives of allylic alcohols react with xanthates in the presence of lauroyl peroxide to give alkenes, often with high stereoselectivity. If the allylic alcohols are themselves derived from aldehydes or ketones, the overall process becomes a synthetic equivalent of the classical Wittig and related olefination reactions.

U2 - 10.1021/ja802899m

DO - 10.1021/ja802899m

M3 - Article

AN - SCOPUS:47349130559

SN - 0002-7863

VL - 130

SP - 8898

EP - 8899

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 28

ER -

Allylic alcohols as radical allylating agents. An overall olefination of aldehydes and ketones

Résumé

Accès au document

Empreinte digitale

Contient cette citation