An enyne metathesis/Diels-Alder reaction sequence towards the synthesis of cup-shaped 5/5/6-tricyclic architectures

Laurent Evanno; Alexandre Deville; Bernard Bodo; Bastien Nay

doi:10.1016/j.tetlet.2007.04.107

An enyne metathesis/Diels-Alder reaction sequence towards the synthesis of cup-shaped 5/5/6-tricyclic architectures

Laurent Evanno
, Alexandre Deville
, Bernard Bodo
, Bastien Nay

CNRS/Museum National d'Histoire Naturelle/IRD/UPMC

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

A strategy to synthesize the 5/5/6-tricyclic framework of presilphiperfolane natural products is described, involving a model dienyne compound (I). The key steps are an enyne metathesis reaction to introduce the diene part and a Diels-Alder cycloaddition to reveal the tricyclic architecture.

langue originale	Anglais
Pages (de - à)	4331-4333
Nombre de pages	3
journal	Tetrahedron Letters
Volume	48
Numéro de publication	25
Les DOIs	https://doi.org/10.1016/j.tetlet.2007.04.107
état	Publié - 18 juin 2007
Modification externe	Oui

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10.1016/j.tetlet.2007.04.107

Contient cette citation

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title = "An enyne metathesis/Diels-Alder reaction sequence towards the synthesis of cup-shaped 5/5/6-tricyclic architectures",

abstract = "A strategy to synthesize the 5/5/6-tricyclic framework of presilphiperfolane natural products is described, involving a model dienyne compound (I). The key steps are an enyne metathesis reaction to introduce the diene part and a Diels-Alder cycloaddition to reveal the tricyclic architecture.",

keywords = "Carbonylation, Catalysis, Diels-Alder cycloaddition, Enyne metathesis, Fused tricyclic structure",

author = "Laurent Evanno and Alexandre Deville and Bernard Bodo and Bastien Nay",

year = "2007",

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AU - Evanno, Laurent

AU - Deville, Alexandre

AU - Bodo, Bernard

AU - Nay, Bastien

PY - 2007/6/18

Y1 - 2007/6/18

N2 - A strategy to synthesize the 5/5/6-tricyclic framework of presilphiperfolane natural products is described, involving a model dienyne compound (I). The key steps are an enyne metathesis reaction to introduce the diene part and a Diels-Alder cycloaddition to reveal the tricyclic architecture.

AB - A strategy to synthesize the 5/5/6-tricyclic framework of presilphiperfolane natural products is described, involving a model dienyne compound (I). The key steps are an enyne metathesis reaction to introduce the diene part and a Diels-Alder cycloaddition to reveal the tricyclic architecture.

KW - Carbonylation

KW - Catalysis

KW - Diels-Alder cycloaddition

KW - Enyne metathesis

KW - Fused tricyclic structure

U2 - 10.1016/j.tetlet.2007.04.107

DO - 10.1016/j.tetlet.2007.04.107

M3 - Article

AN - SCOPUS:34248648753

SN - 0040-4039

VL - 48

SP - 4331

EP - 4333

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 25

ER -

An enyne metathesis/Diels-Alder reaction sequence towards the synthesis of cup-shaped 5/5/6-tricyclic architectures

Résumé

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