Application of the polarizability theory to the calculation of anisotropic circular dichroism spectra

François Hache; Thibault Dartigalongue

doi:10.1016/j.chemphys.2004.05.021

Application of the polarizability theory to the calculation of anisotropic circular dichroism spectra

François Hache
, Thibault Dartigalongue

Institut Polytechnique de Paris

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

We derive a general expression of the circular dichroism spectra of anisotropically distributed chiral molecules in the polarizability framework by introducing a tensorial rotational strength. Example calculation is carried out on an acridine-substituted Tröger base. It is shown that the circular dichroism is very sensitive to the direction propagation of the light beam.

langue originale	Anglais
Pages (de - à)	197-203
Nombre de pages	7
journal	Chemical Physics
Volume	303
Numéro de publication	1-2
Les DOIs	https://doi.org/10.1016/j.chemphys.2004.05.021
état	Publié - 2 août 2004

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10.1016/j.chemphys.2004.05.021

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@article{90ce88695fa64197aed00aa6ed981701,

title = "Application of the polarizability theory to the calculation of anisotropic circular dichroism spectra",

abstract = "We derive a general expression of the circular dichroism spectra of anisotropically distributed chiral molecules in the polarizability framework by introducing a tensorial rotational strength. Example calculation is carried out on an acridine-substituted Tr{\"o}ger base. It is shown that the circular dichroism is very sensitive to the direction propagation of the light beam.",

keywords = "Circular dichroism, Polarizability theory",

author = "Fran{\c c}ois Hache and Thibault Dartigalongue",

year = "2004",

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doi = "10.1016/j.chemphys.2004.05.021",

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T1 - Application of the polarizability theory to the calculation of anisotropic circular dichroism spectra

AU - Hache, François

AU - Dartigalongue, Thibault

PY - 2004/8/2

Y1 - 2004/8/2

N2 - We derive a general expression of the circular dichroism spectra of anisotropically distributed chiral molecules in the polarizability framework by introducing a tensorial rotational strength. Example calculation is carried out on an acridine-substituted Tröger base. It is shown that the circular dichroism is very sensitive to the direction propagation of the light beam.

AB - We derive a general expression of the circular dichroism spectra of anisotropically distributed chiral molecules in the polarizability framework by introducing a tensorial rotational strength. Example calculation is carried out on an acridine-substituted Tröger base. It is shown that the circular dichroism is very sensitive to the direction propagation of the light beam.

KW - Circular dichroism

KW - Polarizability theory

U2 - 10.1016/j.chemphys.2004.05.021

DO - 10.1016/j.chemphys.2004.05.021

M3 - Article

AN - SCOPUS:3042737824

SN - 0301-0104

VL - 303

SP - 197

EP - 203

JO - Chemical Physics

JF - Chemical Physics

IS - 1-2

ER -

Application of the polarizability theory to the calculation of anisotropic circular dichroism spectra

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