Carbon radical attack on a pyrimidine nitrogen. An unusual entry into polycyclic aminopyrimidones

Ling Qin; Zhibo Liu; Samir Z. Zard

doi:10.1021/ol501104h

Carbon radical attack on a pyrimidine nitrogen. An unusual entry into polycyclic aminopyrimidones

Ling Qin
, Zhibo Liu
, Samir Z. Zard

Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

Unprecedented examples of a synthetically useful radical ring closure onto a pyrimidine nitrogen leading to novel, highly functionalized bi- and tricyclic pyrimidone structures are reported. An unexpected hydrogen atom translocation prior to the cyclization step was observed in some cases.

langue originale	Anglais
Pages (de - à)	2966-2969
Nombre de pages	4
journal	Organic Letters
Volume	16
Numéro de publication	11
Les DOIs	https://doi.org/10.1021/ol501104h
état	Publié - 6 juin 2014
Modification externe	Oui

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10.1021/ol501104h

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title = "Carbon radical attack on a pyrimidine nitrogen. An unusual entry into polycyclic aminopyrimidones",

abstract = "Unprecedented examples of a synthetically useful radical ring closure onto a pyrimidine nitrogen leading to novel, highly functionalized bi- and tricyclic pyrimidone structures are reported. An unexpected hydrogen atom translocation prior to the cyclization step was observed in some cases.",

author = "Ling Qin and Zhibo Liu and Zard, \{Samir Z.\}",

year = "2014",

month = jun,

day = "6",

doi = "10.1021/ol501104h",

language = "English",

volume = "16",

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journal = "Organic Letters",

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TY - JOUR

T1 - Carbon radical attack on a pyrimidine nitrogen. An unusual entry into polycyclic aminopyrimidones

AU - Qin, Ling

AU - Liu, Zhibo

AU - Zard, Samir Z.

PY - 2014/6/6

Y1 - 2014/6/6

N2 - Unprecedented examples of a synthetically useful radical ring closure onto a pyrimidine nitrogen leading to novel, highly functionalized bi- and tricyclic pyrimidone structures are reported. An unexpected hydrogen atom translocation prior to the cyclization step was observed in some cases.

AB - Unprecedented examples of a synthetically useful radical ring closure onto a pyrimidine nitrogen leading to novel, highly functionalized bi- and tricyclic pyrimidone structures are reported. An unexpected hydrogen atom translocation prior to the cyclization step was observed in some cases.

UR - https://www.scopus.com/pages/publications/84902089778

U2 - 10.1021/ol501104h

DO - 10.1021/ol501104h

M3 - Article

AN - SCOPUS:84902089778

SN - 1523-7060

VL - 16

SP - 2966

EP - 2969

JO - Organic Letters

JF - Organic Letters

IS - 11

ER -

Carbon radical attack on a pyrimidine nitrogen. An unusual entry into polycyclic aminopyrimidones

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