Cobalt-catalyzed electrophilic amination of arylzincs with N-chloroamines

Xin Qian; Zailu Yu; Audrey Auffrant; Corinne Gosmini

doi:10.1002/chem.201300229

Cobalt-catalyzed electrophilic amination of arylzincs with N-chloroamines

Xin Qian
, Zailu Yu
, Audrey Auffrant
, Corinne Gosmini

CNRS

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

Roles reversed: An efficient cobalt-catalyzed electrophilic amination of arylzinc reagents has been achieved. A variety of functionalized arylzincs and N-chloroamines were coupled under mild conditions (see scheme). Both secondary and tertiary arylamines were obtained in moderate to excellent yields.

langue originale	Anglais
Pages (de - à)	6225-6229
Nombre de pages	5
journal	Chemistry - A European Journal
Volume	19
Numéro de publication	20
Les DOIs	https://doi.org/10.1002/chem.201300229
état	Publié - 10 mai 2013
Modification externe	Oui

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10.1002/chem.201300229

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@article{d1143f5967764b8d8a884ed03fab0ace,

title = "Cobalt-catalyzed electrophilic amination of arylzincs with N-chloroamines",

abstract = "Roles reversed: An efficient cobalt-catalyzed electrophilic amination of arylzinc reagents has been achieved. A variety of functionalized arylzincs and N-chloroamines were coupled under mild conditions (see scheme). Both secondary and tertiary arylamines were obtained in moderate to excellent yields.",

keywords = "C-N coupling, amination, anilines, cobalt, zinc",

author = "Xin Qian and Zailu Yu and Audrey Auffrant and Corinne Gosmini",

year = "2013",

month = may,

day = "10",

doi = "10.1002/chem.201300229",

language = "English",

volume = "19",

pages = "6225--6229",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "John Wiley and Sons Inc",

number = "20",

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TY - JOUR

T1 - Cobalt-catalyzed electrophilic amination of arylzincs with N-chloroamines

AU - Qian, Xin

AU - Yu, Zailu

AU - Auffrant, Audrey

AU - Gosmini, Corinne

PY - 2013/5/10

Y1 - 2013/5/10

N2 - Roles reversed: An efficient cobalt-catalyzed electrophilic amination of arylzinc reagents has been achieved. A variety of functionalized arylzincs and N-chloroamines were coupled under mild conditions (see scheme). Both secondary and tertiary arylamines were obtained in moderate to excellent yields.

AB - Roles reversed: An efficient cobalt-catalyzed electrophilic amination of arylzinc reagents has been achieved. A variety of functionalized arylzincs and N-chloroamines were coupled under mild conditions (see scheme). Both secondary and tertiary arylamines were obtained in moderate to excellent yields.

KW - C-N coupling

KW - amination

KW - anilines

KW - cobalt

KW - zinc

U2 - 10.1002/chem.201300229

DO - 10.1002/chem.201300229

M3 - Article

C2 - 23526669

AN - SCOPUS:84877310898

SN - 0947-6539

VL - 19

SP - 6225

EP - 6229

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 20

ER -

Cobalt-catalyzed electrophilic amination of arylzincs with N-chloroamines

Résumé

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