Résumé
Collisional narrowing due to line-mixing effects are studied in the v3 and 3v3 bands of CO2 perturbed by He and Ar at elevated pressure. The results of computations using an energy-corrected sudden approach are compared with measurements. The model enables the correct prediction of the decrease in the measured bandwidth with increasing density which is due to interbranch (R ↔ P) coupling and which is analyzed theoretically in the infrared.
| langue originale | Anglais |
|---|---|
| Pages (de - à) | 353-356 |
| Nombre de pages | 4 |
| journal | Chemical Physics Letters |
| Volume | 261 |
| Numéro de publication | 3 |
| Les DOIs | |
| état | Publié - 18 oct. 1996 |
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