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Collisional narrowing of gas phase infrared bands of CO2 at high density

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Résumé

Collisional narrowing due to line-mixing effects are studied in the v3 and 3v3 bands of CO2 perturbed by He and Ar at elevated pressure. The results of computations using an energy-corrected sudden approach are compared with measurements. The model enables the correct prediction of the decrease in the measured bandwidth with increasing density which is due to interbranch (R ↔ P) coupling and which is analyzed theoretically in the infrared.

langue originaleAnglais
Pages (de - à)353-356
Nombre de pages4
journalChemical Physics Letters
Volume261
Numéro de publication3
Les DOIs
étatPublié - 18 oct. 1996

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