Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design

G. Cabochea; J. F. Hochepied; P. Piccardo; K. P. Rzybylski; R. Ruckdäschel; M. R. Ardigó; E. Fatome; S. Chevalier; A. Perron; L. Combemale; M. Palard; J. Prazuch; T. Brylewski

doi:10.1149/1.3205593

Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design

G. Cabochea
, J. F. Hochepied
, P. Piccardo
, K. P. Rzybylski
, R. Ruckdäschel
, M. R. Ardigó
, E. Fatome
, S. Chevalier
, A. Perron
, L. Combemale
, M. Palard
, J. Prazuch
, T. Brylewski

Centre de Recherches de Climatologie, CNRS UMR 5210, Université de Bourgogne
Mines ParisTech
University of Genoa
Agh University of Science and Technology Faculty of Computer Science
DLR

Résultats de recherche: Le chapitre dans un livre, un rapport, une anthologie ou une collection › Contribution à une conférence › Revue par des pairs

Résumé

The IDEAL-Cell project aims at developing an innovative and competitive concept for fuel cell operating between 600-700°C. It is based on the junction between a PCFC anode/electrolyte part and a SOFC electrolyte/cathode, through a mixed porous ceramic membrane. Cathode materials are: La _0.60Sr_0.40CoO_3-δ (LSCF40) or La _0.60Sr_0.40Co_0.20Fe_0.80O _3-δ (LSCF48); electrolyte materials are: Ce _0.85Y_0.15O_2-δ (YDC15) and BaCe _0.85Y_0.15O_3-δ (BCY15). Ni-BCY15 cermet is the anode material. The central membrane is made of BCY15-YDC15 mixture. Good compatibility was observed at electrode/electrolyte cathode interface after long term ageing (20 h/1100°C following by 500 h/700°C) and no new phase was detected. Concerning the dual membrane BCY15-YDC15, a good adhesion was obtained between these two electrolyte materials. Finally, reactivity between LSCF40/48 and Crofer 22 APU (selected as first generation interconnect material) was studied in oxidizing atmosphere (1 h/1000°C following by 200 h/700°C). SrCrO₄ formation was observed due to the diffusion of Cr and reaction with Sr from the cathode material.

langue originale	Anglais
titre	ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI)
Pages	763-772
Nombre de pages	10
Edition	2 PART 1
Les DOIs	https://doi.org/10.1149/1.3205593
état	Publié - 1 déc. 2009
Modification externe	Oui
Evénement	11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting - Vienna, Autriche Durée: 4 oct. 2009 → 9 oct. 2009

Série de publications

Nom	ECS Transactions
nombre	2 PART 1
Volume	25
ISSN (imprimé)	1938-5862
ISSN (Electronique)	1938-6737

Une conférence

Une conférence	11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting
Pays/Territoire	Autriche
La ville	Vienna
période	4/10/09 → 9/10/09

Accès au document

10.1149/1.3205593

Contient cette citation

Cabochea, G., Hochepied, J. F., Piccardo, P., Rzybylski, K. P., Ruckdäschel, R., Ardigó, M. R., Fatome, E., Chevalier, S., Perron, A., Combemale, L., Palard, M., Prazuch, J., & Brylewski, T. (2009). Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design. Dans ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI) (2 PART 1 Ed., p. 763-772). (ECS Transactions; Vol 25, Numéro 2 PART 1). https://doi.org/10.1149/1.3205593

@inproceedings{0c346bd9bb604fea8a94e4a5c6284d18,

title = "Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design",

abstract = "The IDEAL-Cell project aims at developing an innovative and competitive concept for fuel cell operating between 600-700°C. It is based on the junction between a PCFC anode/electrolyte part and a SOFC electrolyte/cathode, through a mixed porous ceramic membrane. Cathode materials are: La 0.60Sr0.40CoO3-δ (LSCF40) or La 0.60Sr0.40Co0.20Fe0.80O 3-δ (LSCF48); electrolyte materials are: Ce 0.85Y0.15O2-δ (YDC15) and BaCe 0.85Y0.15O3-δ (BCY15). Ni-BCY15 cermet is the anode material. The central membrane is made of BCY15-YDC15 mixture. Good compatibility was observed at electrode/electrolyte cathode interface after long term ageing (20 h/1100°C following by 500 h/700°C) and no new phase was detected. Concerning the dual membrane BCY15-YDC15, a good adhesion was obtained between these two electrolyte materials. Finally, reactivity between LSCF40/48 and Crofer 22 APU (selected as first generation interconnect material) was studied in oxidizing atmosphere (1 h/1000°C following by 200 h/700°C). SrCrO4 formation was observed due to the diffusion of Cr and reaction with Sr from the cathode material.",

author = "G. Cabochea and Hochepied, \{J. F.\} and P. Piccardo and Rzybylski, \{K. P.\} and R. Ruckd{\"a}schel and Ardig{\'o}, \{M. R.\} and E. Fatome and S. Chevalier and A. Perron and L. Combemale and M. Palard and J. Prazuch and T. Brylewski",

year = "2009",

month = dec,

day = "1",

doi = "10.1149/1.3205593",

language = "English",

isbn = "9781566777391",

series = "ECS Transactions",

number = "2 PART 1",

pages = "763--772",

booktitle = "ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI)",

edition = "2 PART 1",

note = "11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting ; Conference date: 04-10-2009 Through 09-10-2009",

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Cabochea, G, Hochepied, JF, Piccardo, P, Rzybylski, KP, Ruckdäschel, R, Ardigó, MR, Fatome, E, Chevalier, S, Perron, A, Combemale, L, Palard, M, Prazuch, J & Brylewski, T 2009, Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design. Dans ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI). 2 PART 1 edn, ECS Transactions, Numéro 2 PART 1, VOL. 25, p. 763-772, 11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting, Vienna, Autriche, 4/10/09. https://doi.org/10.1149/1.3205593

Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design. / Cabochea, G.; Hochepied, J. F.; Piccardo, P. et al.
ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI). 2 PART 1. Ed. 2009. p. 763-772 (ECS Transactions; Vol 25, Numéro 2 PART 1).

Résultats de recherche: Le chapitre dans un livre, un rapport, une anthologie ou une collection › Contribution à une conférence › Revue par des pairs

TY - GEN

T1 - Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design

AU - Cabochea, G.

AU - Hochepied, J. F.

AU - Piccardo, P.

AU - Rzybylski, K. P.

AU - Ruckdäschel, R.

AU - Ardigó, M. R.

AU - Fatome, E.

AU - Chevalier, S.

AU - Perron, A.

AU - Combemale, L.

AU - Palard, M.

AU - Prazuch, J.

AU - Brylewski, T.

PY - 2009/12/1

Y1 - 2009/12/1

N2 - The IDEAL-Cell project aims at developing an innovative and competitive concept for fuel cell operating between 600-700°C. It is based on the junction between a PCFC anode/electrolyte part and a SOFC electrolyte/cathode, through a mixed porous ceramic membrane. Cathode materials are: La 0.60Sr0.40CoO3-δ (LSCF40) or La 0.60Sr0.40Co0.20Fe0.80O 3-δ (LSCF48); electrolyte materials are: Ce 0.85Y0.15O2-δ (YDC15) and BaCe 0.85Y0.15O3-δ (BCY15). Ni-BCY15 cermet is the anode material. The central membrane is made of BCY15-YDC15 mixture. Good compatibility was observed at electrode/electrolyte cathode interface after long term ageing (20 h/1100°C following by 500 h/700°C) and no new phase was detected. Concerning the dual membrane BCY15-YDC15, a good adhesion was obtained between these two electrolyte materials. Finally, reactivity between LSCF40/48 and Crofer 22 APU (selected as first generation interconnect material) was studied in oxidizing atmosphere (1 h/1000°C following by 200 h/700°C). SrCrO4 formation was observed due to the diffusion of Cr and reaction with Sr from the cathode material.

AB - The IDEAL-Cell project aims at developing an innovative and competitive concept for fuel cell operating between 600-700°C. It is based on the junction between a PCFC anode/electrolyte part and a SOFC electrolyte/cathode, through a mixed porous ceramic membrane. Cathode materials are: La 0.60Sr0.40CoO3-δ (LSCF40) or La 0.60Sr0.40Co0.20Fe0.80O 3-δ (LSCF48); electrolyte materials are: Ce 0.85Y0.15O2-δ (YDC15) and BaCe 0.85Y0.15O3-δ (BCY15). Ni-BCY15 cermet is the anode material. The central membrane is made of BCY15-YDC15 mixture. Good compatibility was observed at electrode/electrolyte cathode interface after long term ageing (20 h/1100°C following by 500 h/700°C) and no new phase was detected. Concerning the dual membrane BCY15-YDC15, a good adhesion was obtained between these two electrolyte materials. Finally, reactivity between LSCF40/48 and Crofer 22 APU (selected as first generation interconnect material) was studied in oxidizing atmosphere (1 h/1000°C following by 200 h/700°C). SrCrO4 formation was observed due to the diffusion of Cr and reaction with Sr from the cathode material.

U2 - 10.1149/1.3205593

DO - 10.1149/1.3205593

M3 - Conference contribution

AN - SCOPUS:77649247227

SN - 9781566777391

T3 - ECS Transactions

SP - 763

EP - 772

BT - ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI)

T2 - 11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting

Y2 - 4 October 2009 through 9 October 2009

ER -

Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design

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