Complexes featuring tridentate iminophosphorane ligands: Synthesis, reactivity, and catalysis

Thibault Tannoux; Audrey Auffrant

doi:10.1016/j.ccr.2022.214845

Complexes featuring tridentate iminophosphorane ligands: Synthesis, reactivity, and catalysis

Thibault Tannoux
, Audrey Auffrant

CNRS

Résultats de recherche: Contribution à un journal › Article de révision › Revue par des pairs

Résumé

Even if iminophosphoranes (R₃P = NR′) were described more than a century ago they remain much less investigated in coordination chemistry than phosphine or N-heterocyclic based ligands, while they present like the latter a strong electron-donor ability. The variety of complexes supported by tridentate iminophosphorane (P[dbnd]N) ligands is reviewed based on the nature of the coordination sites and their reactivity and/or catalytic applications are discussed.

langue originale	Anglais
Numéro d'article	214845
journal	Coordination Chemistry Reviews
Volume	474
Les DOIs	https://doi.org/10.1016/j.ccr.2022.214845
état	Publié - 1 janv. 2023
Modification externe	Oui

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10.1016/j.ccr.2022.214845

Contient cette citation

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title = "Complexes featuring tridentate iminophosphorane ligands: Synthesis, reactivity, and catalysis",

abstract = "Even if iminophosphoranes (R3P = NR′) were described more than a century ago they remain much less investigated in coordination chemistry than phosphine or N-heterocyclic based ligands, while they present like the latter a strong electron-donor ability. The variety of complexes supported by tridentate iminophosphorane (P[dbnd]N) ligands is reviewed based on the nature of the coordination sites and their reactivity and/or catalytic applications are discussed.",

keywords = "Catalysis, Coupling reactions, Iminophosphorane, Polymerization, Tridentate ligand",

author = "Thibault Tannoux and Audrey Auffrant",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",

year = "2023",

month = jan,

day = "1",

doi = "10.1016/j.ccr.2022.214845",

language = "English",

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TY - JOUR

T1 - Complexes featuring tridentate iminophosphorane ligands

T2 - Synthesis, reactivity, and catalysis

AU - Tannoux, Thibault

AU - Auffrant, Audrey

PY - 2023/1/1

Y1 - 2023/1/1

N2 - Even if iminophosphoranes (R3P = NR′) were described more than a century ago they remain much less investigated in coordination chemistry than phosphine or N-heterocyclic based ligands, while they present like the latter a strong electron-donor ability. The variety of complexes supported by tridentate iminophosphorane (P[dbnd]N) ligands is reviewed based on the nature of the coordination sites and their reactivity and/or catalytic applications are discussed.

AB - Even if iminophosphoranes (R3P = NR′) were described more than a century ago they remain much less investigated in coordination chemistry than phosphine or N-heterocyclic based ligands, while they present like the latter a strong electron-donor ability. The variety of complexes supported by tridentate iminophosphorane (P[dbnd]N) ligands is reviewed based on the nature of the coordination sites and their reactivity and/or catalytic applications are discussed.

KW - Catalysis

KW - Coupling reactions

KW - Iminophosphorane

KW - Polymerization

KW - Tridentate ligand

U2 - 10.1016/j.ccr.2022.214845

DO - 10.1016/j.ccr.2022.214845

M3 - Review article

AN - SCOPUS:85140751140

SN - 0010-8545

VL - 474

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

M1 - 214845

ER -

Complexes featuring tridentate iminophosphorane ligands: Synthesis, reactivity, and catalysis

Résumé

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