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Conductivity dependence on oxygen partial pressure and transport number measurements of La2Mo2O9

  • A. Tarancón
  • , G. Dezanneau
  • , A. Morata
  • , F. Peiró
  • , J. R. Morante
  • , T. Norby
  • University of Barcelona
  • University of Oslo

Résultats de recherche: Contribution à un journalArticle de conférenceRevue par des pairs

Résumé

Transport number measurements and impedance spectroscopy in controlled temperature and atmosphere were used to investigate the electrical properties of La2Mo2O9 sintered samples. These samples were prepared from nanocrystalline La2Mo2O9 powders as obtained from a new soft chemistry route involving the polymerisation of acrylamide. By means of the electromotive force method measurements, the sintered compound was found mainly oxygen conductor in the range of 400°C-800°C with oxide-ion transport number greater than 0.99. The effect of the oxygen partial pressure on the electrical conductivity of La 2Mo2O9 was investigated by impedance spectroscopy from 1 to 10-22 atm, showing a highly stable conduction properties up to 10-17 atm at 800°C.

langue originaleAnglais
Numéro d'articleS6.5
Pages (de - à)103-108
Nombre de pages6
journalMaterials Research Society Symposium - Proceedings
Volume822
Les DOIs
étatPublié - 1 janv. 2004
Modification externeOui
EvénementNanostructured Materials in Alternative Energy Devices - San Francisco, CA, États-Unis
Durée: 13 avr. 200415 avr. 2004

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