Coupling between molecular rotations and OH···O motions in liquid water: Theory and experiment

G. Gallot; S. Bratos; S. Pommeret; N. Lascoux; J. Cl Leicknam; M. Koziński; W. Amir; G. M. Gale

doi:10.1063/1.1522378

Coupling between molecular rotations and OH···O motions in liquid water: Theory and experiment

G. Gallot
, S. Bratos
, S. Pommeret
, N. Lascoux
, J. Cl Leicknam
, M. Koziński
, W. Amir
, G. M. Gale

Université Pierre et Marie Curie
Institut Pierre Simon Laplace, CNRS and CEA
Institut Polytechnique de Paris

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

A new statistical theory of couplings between molecular rotations and the OH···O motions. As such, the correlation function approach is employed all along as well as a special type of expansion in whcih the energy of coupling between rotational and OH···O motions is the expansion parameter. It is found that the lifetime fo the OH···O bonds in water is shown to be rotation limited.

langue originale	Anglais
Pages (de - à)	11301-11309
Nombre de pages	9
journal	Journal of Chemical Physics
Volume	117
Numéro de publication	24
Les DOIs	https://doi.org/10.1063/1.1522378
état	Publié - 22 déc. 2002

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10.1063/1.1522378

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title = "Coupling between molecular rotations and OH···O motions in liquid water: Theory and experiment",

abstract = "A new statistical theory of couplings between molecular rotations and the OH···O motions. As such, the correlation function approach is employed all along as well as a special type of expansion in whcih the energy of coupling between rotational and OH···O motions is the expansion parameter. It is found that the lifetime fo the OH···O bonds in water is shown to be rotation limited.",

author = "G. Gallot and S. Bratos and S. Pommeret and N. Lascoux and Leicknam, \{J. Cl\} and M. Kozi{\'n}ski and W. Amir and Gale, \{G. M.\}",

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T2 - Theory and experiment

AU - Gallot, G.

AU - Bratos, S.

AU - Pommeret, S.

AU - Lascoux, N.

AU - Leicknam, J. Cl

AU - Koziński, M.

AU - Amir, W.

AU - Gale, G. M.

PY - 2002/12/22

Y1 - 2002/12/22

N2 - A new statistical theory of couplings between molecular rotations and the OH···O motions. As such, the correlation function approach is employed all along as well as a special type of expansion in whcih the energy of coupling between rotational and OH···O motions is the expansion parameter. It is found that the lifetime fo the OH···O bonds in water is shown to be rotation limited.

AB - A new statistical theory of couplings between molecular rotations and the OH···O motions. As such, the correlation function approach is employed all along as well as a special type of expansion in whcih the energy of coupling between rotational and OH···O motions is the expansion parameter. It is found that the lifetime fo the OH···O bonds in water is shown to be rotation limited.

U2 - 10.1063/1.1522378

DO - 10.1063/1.1522378

M3 - Article

AN - SCOPUS:0037461525

SN - 0021-9606

VL - 117

SP - 11301

EP - 11309

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 24

ER -

Coupling between molecular rotations and OH···O motions in liquid water: Theory and experiment

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