Cyano(ethoxycarbonothioylthio)methyl benzoate: A novel one-carbon radical equivalent

Sharanjeet K. Bagal; Michiel De Greef; Samir Z. Zard

doi:10.1021/ol052634m

Cyano(ethoxycarbonothioylthio)methyl benzoate: A novel one-carbon radical equivalent

Sharanjeet K. Bagal
, Michiel De Greef
, Samir Z. Zard

Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

21 Citations (Scopus)

Résumé

(Chemical Equation Presented) Cyano(ethoxycarbonothioylthio)methyl benzoate 3 has been prepared and shown to be an excellent one-carbon radical equivalent that can be applied for the introduction of an acyl unit via xanthate transfer radical addition to olefins. The corresponding adducts can be further elaborated. A rare 1,5-nitrile translocation was also observed during the study.

langue originale	Anglais
Pages (de - à)	147-150
Nombre de pages	4
journal	Organic Letters
Volume	8
Numéro de publication	1
Les DOIs	https://doi.org/10.1021/ol052634m
état	Publié - 5 janv. 2006
Modification externe	Oui

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10.1021/ol052634m

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title = "Cyano(ethoxycarbonothioylthio)methyl benzoate: A novel one-carbon radical equivalent",

abstract = "(Chemical Equation Presented) Cyano(ethoxycarbonothioylthio)methyl benzoate 3 has been prepared and shown to be an excellent one-carbon radical equivalent that can be applied for the introduction of an acyl unit via xanthate transfer radical addition to olefins. The corresponding adducts can be further elaborated. A rare 1,5-nitrile translocation was also observed during the study.",

author = "Bagal, \{Sharanjeet K.\} and \{De Greef\}, Michiel and Zard, \{Samir Z.\}",

year = "2006",

month = jan,

day = "5",

doi = "10.1021/ol052634m",

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volume = "8",

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journal = "Organic Letters",

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TY - JOUR

T1 - Cyano(ethoxycarbonothioylthio)methyl benzoate

T2 - A novel one-carbon radical equivalent

AU - Bagal, Sharanjeet K.

AU - De Greef, Michiel

AU - Zard, Samir Z.

PY - 2006/1/5

Y1 - 2006/1/5

N2 - (Chemical Equation Presented) Cyano(ethoxycarbonothioylthio)methyl benzoate 3 has been prepared and shown to be an excellent one-carbon radical equivalent that can be applied for the introduction of an acyl unit via xanthate transfer radical addition to olefins. The corresponding adducts can be further elaborated. A rare 1,5-nitrile translocation was also observed during the study.

AB - (Chemical Equation Presented) Cyano(ethoxycarbonothioylthio)methyl benzoate 3 has been prepared and shown to be an excellent one-carbon radical equivalent that can be applied for the introduction of an acyl unit via xanthate transfer radical addition to olefins. The corresponding adducts can be further elaborated. A rare 1,5-nitrile translocation was also observed during the study.

U2 - 10.1021/ol052634m

DO - 10.1021/ol052634m

M3 - Article

AN - SCOPUS:30944453036

SN - 1523-7060

VL - 8

SP - 147

EP - 150

JO - Organic Letters

JF - Organic Letters

IS - 1

ER -

Cyano(ethoxycarbonothioylthio)methyl benzoate: A novel one-carbon radical equivalent

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