Diazo Esters Addition to Trifluoropyruvamides: New Access to Highly Functionalized Trifluoromethyl Epoxides and Diazo Compounds

Laurent El Kaim; Cyril Ollivier

doi:10.1055/s-1997-5760

Diazo Esters Addition to Trifluoropyruvamides: New Access to Highly Functionalized Trifluoromethyl Epoxides and Diazo Compounds

Laurent El Kaim
, Cyril Ollivier

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

Trifluoropyruvamides in their hydrated form readily react with diazo esters affording new trifluoromethyl epoxides. Activating the pyruvamide with trifluoroacetic anhydride leads to a complete change in selectivity with the formation of a new diazo compound.

langue originale	Anglais
Pages (de - à)	797-798
Nombre de pages	2
journal	Synlett
Volume	1997
Numéro de publication	7
Les DOIs	https://doi.org/10.1055/s-1997-5760
état	Publié - 1 janv. 1997

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10.1055/s-1997-5760

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@article{f958bc11d05d41638952a1237f16d131,

title = "Diazo Esters Addition to Trifluoropyruvamides: New Access to Highly Functionalized Trifluoromethyl Epoxides and Diazo Compounds",

abstract = "Trifluoropyruvamides in their hydrated form readily react with diazo esters affording new trifluoromethyl epoxides. Activating the pyruvamide with trifluoroacetic anhydride leads to a complete change in selectivity with the formation of a new diazo compound.",

author = "\{El Kaim\}, Laurent and Cyril Ollivier",

year = "1997",

month = jan,

day = "1",

doi = "10.1055/s-1997-5760",

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volume = "1997",

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journal = "Synlett",

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TY - JOUR

T1 - Diazo Esters Addition to Trifluoropyruvamides

T2 - New Access to Highly Functionalized Trifluoromethyl Epoxides and Diazo Compounds

AU - El Kaim, Laurent

AU - Ollivier, Cyril

PY - 1997/1/1

Y1 - 1997/1/1

N2 - Trifluoropyruvamides in their hydrated form readily react with diazo esters affording new trifluoromethyl epoxides. Activating the pyruvamide with trifluoroacetic anhydride leads to a complete change in selectivity with the formation of a new diazo compound.

AB - Trifluoropyruvamides in their hydrated form readily react with diazo esters affording new trifluoromethyl epoxides. Activating the pyruvamide with trifluoroacetic anhydride leads to a complete change in selectivity with the formation of a new diazo compound.

U2 - 10.1055/s-1997-5760

DO - 10.1055/s-1997-5760

M3 - Article

AN - SCOPUS:0010541713

SN - 0936-5214

VL - 1997

SP - 797

EP - 798

JO - Synlett

JF - Synlett

IS - 7

ER -

Diazo Esters Addition to Trifluoropyruvamides: New Access to Highly Functionalized Trifluoromethyl Epoxides and Diazo Compounds

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