Dibenzophosphasemibullvalene

Jens Geier; Gilles Frison; Hansjörg Grützmacher

doi:10.1002/anie.200351388

Dibenzophosphasemibullvalene

Jens Geier
, Gilles Frison
, Hansjörg Grützmacher

ETH Zurich
CNRS

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

17 Citations (Scopus)

Résumé

Strain is not to blame: Controlled thermolysis of 1 afforded dibenzo-1-phosphasemibullvalene 2 (see scheme). This unstable compound can be stabilized as a ligand in the complex [W(CO)₅(2)]. Although the sum of bond angles at phosphorus (220°) is very small, 2 is only a little strained.

langue originale	Anglais
Pages (de - à)	3955-3957
Nombre de pages	3
journal	Angewandte Chemie - International Edition
Volume	42
Numéro de publication	33
Les DOIs	https://doi.org/10.1002/anie.200351388
état	Publié - 25 août 2003
Modification externe	Oui

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10.1002/anie.200351388

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@article{9806a5be7b224f92ac44142481bde68e,

title = "Dibenzophosphasemibullvalene",

abstract = "Strain is not to blame: Controlled thermolysis of 1 afforded dibenzo-1-phosphasemibullvalene 2 (see scheme). This unstable compound can be stabilized as a ligand in the complex [W(CO)5(2)]. Although the sum of bond angles at phosphorus (220°) is very small, 2 is only a little strained.",

author = "Jens Geier and Gilles Frison and Hansj{\"o}rg Gr{\"u}tzmacher",

year = "2003",

month = aug,

day = "25",

doi = "10.1002/anie.200351388",

language = "English",

volume = "42",

pages = "3955--3957",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "33",

}

TY - JOUR

T1 - Dibenzophosphasemibullvalene

AU - Geier, Jens

AU - Frison, Gilles

AU - Grützmacher, Hansjörg

PY - 2003/8/25

Y1 - 2003/8/25

N2 - Strain is not to blame: Controlled thermolysis of 1 afforded dibenzo-1-phosphasemibullvalene 2 (see scheme). This unstable compound can be stabilized as a ligand in the complex [W(CO)5(2)]. Although the sum of bond angles at phosphorus (220°) is very small, 2 is only a little strained.

AB - Strain is not to blame: Controlled thermolysis of 1 afforded dibenzo-1-phosphasemibullvalene 2 (see scheme). This unstable compound can be stabilized as a ligand in the complex [W(CO)5(2)]. Although the sum of bond angles at phosphorus (220°) is very small, 2 is only a little strained.

U2 - 10.1002/anie.200351388

DO - 10.1002/anie.200351388

M3 - Article

AN - SCOPUS:0042819642

SN - 1433-7851

VL - 42

SP - 3955

EP - 3957

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 33

ER -

Dibenzophosphasemibullvalene

Résumé

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