Dual Photocatalysis for the Straightforward Coupling of Thiosugars and Arylsulfoximines: Towards Unprecedented Cyclic Heteroatomic Structures

Thibaut Duhail; Mingxiang Zhu; Coralie Rombault; Guillaume Dagousset; Samir Messaoudi; Emmanuel Magnier; Elsa Anselmi

doi:10.1002/ejoc.202200173

Dual Photocatalysis for the Straightforward Coupling of Thiosugars and Arylsulfoximines: Towards Unprecedented Cyclic Heteroatomic Structures

Thibaut Duhail
, Mingxiang Zhu
, Coralie Rombault
, Guillaume Dagousset
, Samir Messaoudi
, Emmanuel Magnier
, Elsa Anselmi

Université Versailles-Saint Quentin
Université Paris-Saclay
Université de Tours

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

A general, scalable and easy to implement protocol is described for the coupling of thiosugars and various ortho-functionalized S-aryl S-perfluoroalkyl sulfoximines. This dual photocatalysis methodology was developed with a commercial hydrogen atom transfer reagent and produced key structures that were transformed into original cyclic skeletons bearing previously undescribed chemical functions.

langue originale	Anglais
Numéro d'article	e202200173
journal	European Journal of Organic Chemistry
Volume	2022
Numéro de publication	29
Les DOIs	https://doi.org/10.1002/ejoc.202200173
état	Publié - 5 août 2022
Modification externe	Oui

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10.1002/ejoc.202200173

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title = "Dual Photocatalysis for the Straightforward Coupling of Thiosugars and Arylsulfoximines: Towards Unprecedented Cyclic Heteroatomic Structures",

abstract = "A general, scalable and easy to implement protocol is described for the coupling of thiosugars and various ortho-functionalized S-aryl S-perfluoroalkyl sulfoximines. This dual photocatalysis methodology was developed with a commercial hydrogen atom transfer reagent and produced key structures that were transformed into original cyclic skeletons bearing previously undescribed chemical functions.",

keywords = "Dual photocatalysis, Fluorine, Heterocycles, S-arylsulfoximines, Thioglycosides",

author = "Thibaut Duhail and Mingxiang Zhu and Coralie Rombault and Guillaume Dagousset and Samir Messaoudi and Emmanuel Magnier and Elsa Anselmi",

note = "Publisher Copyright: {\textcopyright} 2022 Wiley-VCH GmbH.",

year = "2022",

month = aug,

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doi = "10.1002/ejoc.202200173",

language = "English",

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Dual Photocatalysis for the Straightforward Coupling of Thiosugars and Arylsulfoximines: Towards Unprecedented Cyclic Heteroatomic Structures. / Duhail, Thibaut; Zhu, Mingxiang; Rombault, Coralie et al.
Dans: European Journal of Organic Chemistry, Vol 2022, Numéro 29, e202200173, 05.08.2022.

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

TY - JOUR

T1 - Dual Photocatalysis for the Straightforward Coupling of Thiosugars and Arylsulfoximines

T2 - Towards Unprecedented Cyclic Heteroatomic Structures

AU - Duhail, Thibaut

AU - Zhu, Mingxiang

AU - Rombault, Coralie

AU - Dagousset, Guillaume

AU - Messaoudi, Samir

AU - Magnier, Emmanuel

AU - Anselmi, Elsa

PY - 2022/8/5

Y1 - 2022/8/5

N2 - A general, scalable and easy to implement protocol is described for the coupling of thiosugars and various ortho-functionalized S-aryl S-perfluoroalkyl sulfoximines. This dual photocatalysis methodology was developed with a commercial hydrogen atom transfer reagent and produced key structures that were transformed into original cyclic skeletons bearing previously undescribed chemical functions.

AB - A general, scalable and easy to implement protocol is described for the coupling of thiosugars and various ortho-functionalized S-aryl S-perfluoroalkyl sulfoximines. This dual photocatalysis methodology was developed with a commercial hydrogen atom transfer reagent and produced key structures that were transformed into original cyclic skeletons bearing previously undescribed chemical functions.

KW - Dual photocatalysis

KW - Fluorine

KW - Heterocycles

KW - S-arylsulfoximines

KW - Thioglycosides

U2 - 10.1002/ejoc.202200173

DO - 10.1002/ejoc.202200173

M3 - Article

AN - SCOPUS:85128625455

SN - 1434-193X

VL - 2022

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 29

M1 - e202200173

ER -

Dual Photocatalysis for the Straightforward Coupling of Thiosugars and Arylsulfoximines: Towards Unprecedented Cyclic Heteroatomic Structures

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