Résumé
The preparation and characterization of high-surface-area ruthenium oxide (RuO2)/multi-walled carbon nanotubes (MWCNTs) composite electrodes for use in supercapacitors is reported in this work. The RuO2/MWCNTs composites were prepared by the polyol process of RuO2 into MWCNTs and by Ru annealing in air before mixed with MWCNTs. The chemically oxidized and annealed Ru nanoparticles contribute a pseudocapacitance to the electrodes and dramatically improve the energy storage characteristics of the MWCNTs. These composites annealed at 200 °C demonstrate specific capacitances in excess of 130 F/g in comparison to 80 F/g for pristine MWCNTs. The annealing temperature is found to play an important role, as it affects the electrochemical performance of annealed RuO2/MWCNTs composites critically due to its influence on the diffusion of protons into the structure.
| langue originale | Anglais |
|---|---|
| Pages (de - à) | 65-69 |
| Nombre de pages | 5 |
| journal | Materials Science and Engineering: B |
| Volume | 167 |
| Numéro de publication | 1 |
| Les DOIs | |
| état | Publié - 25 févr. 2010 |
| Modification externe | Oui |
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