Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures

François Terrier; Sami Lakhdar; Régis Goumont; Taoufik Boubaker; Erwin Buncel

doi:10.1039/b410356d

Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures

François Terrier
, Sami Lakhdar
, Régis Goumont
, Taoufik Boubaker
, Erwin Buncel

Université Versailles-Saint Quentin
Faculté des Sciences de Monastir
Department of Chemistry
Queen's University

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

28 Citations (Scopus)

Résumé

Using appropriate sets of reference nucleophiles, the reactivity of neutral electrophiles of widely different reactivity and structure has been ranked on the comprehensive electrophilicity scale of Mayr (Acc. Chem. Res., 2003, 36, 66), holding promise of a general rationalization of σ-complexation processes and related S_NAr substitutions.

langue originale	Anglais
Pages (de - à)	2586-2587
Nombre de pages	2
journal	Chemical Communications
Numéro de publication	22
Les DOIs	https://doi.org/10.1039/b410356d
état	Publié - 21 nov. 2004
Modification externe	Oui

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10.1039/b410356d

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title = "Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures",

abstract = "Using appropriate sets of reference nucleophiles, the reactivity of neutral electrophiles of widely different reactivity and structure has been ranked on the comprehensive electrophilicity scale of Mayr (Acc. Chem. Res., 2003, 36, 66), holding promise of a general rationalization of σ-complexation processes and related SNAr substitutions.",

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T1 - Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures

AU - Terrier, François

AU - Lakhdar, Sami

AU - Goumont, Régis

AU - Boubaker, Taoufik

AU - Buncel, Erwin

PY - 2004/11/21

Y1 - 2004/11/21

N2 - Using appropriate sets of reference nucleophiles, the reactivity of neutral electrophiles of widely different reactivity and structure has been ranked on the comprehensive electrophilicity scale of Mayr (Acc. Chem. Res., 2003, 36, 66), holding promise of a general rationalization of σ-complexation processes and related SNAr substitutions.

AB - Using appropriate sets of reference nucleophiles, the reactivity of neutral electrophiles of widely different reactivity and structure has been ranked on the comprehensive electrophilicity scale of Mayr (Acc. Chem. Res., 2003, 36, 66), holding promise of a general rationalization of σ-complexation processes and related SNAr substitutions.

UR - https://www.scopus.com/pages/publications/9944236825

U2 - 10.1039/b410356d

DO - 10.1039/b410356d

M3 - Article

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JO - Chemical Communications

JF - Chemical Communications

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Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures

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