Enantioselective Au(i)-catalyzed dearomatization of 1-naphthols with allenamides through Tethered Counterion-Directed Catalysis

Yunliang Yu; Zhenhao Zhang; Arnaud Voituriez; Nicolas Rabasso; Gilles Frison; Angela Marinetti; Xavier Guinchard

doi:10.1039/d1cc04088j

Enantioselective Au(i)-catalyzed dearomatization of 1-naphthols with allenamides through Tethered Counterion-Directed Catalysis

Yunliang Yu
, Zhenhao Zhang
, Arnaud Voituriez
, Nicolas Rabasso
, Gilles Frison
, Angela Marinetti
, Xavier Guinchard

École Polytechnique

Université Paris-Saclay

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

The Tethered Counterion-Directed Catalysis (TCDC) approach has been applied to the enantioselective Au(i) catalyzed dearomatizations of 1-naphthols with allenamides. Stereocontrol is ensured by the intramolecular ion-pairing between the chiral gold-tethered phosphate and an iminium unit, that provides a rigid, well-defined chiral environment to the key electrophilic intermediate.

langue originale	Anglais
Pages (de - à)	10779-10782
Nombre de pages	4
journal	Chemical Communications
Volume	57
Numéro de publication	82
Les DOIs	https://doi.org/10.1039/d1cc04088j
état	Publié - 21 oct. 2021

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10.1039/d1cc04088j

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title = "Enantioselective Au(i)-catalyzed dearomatization of 1-naphthols with allenamides through Tethered Counterion-Directed Catalysis",

abstract = "The Tethered Counterion-Directed Catalysis (TCDC) approach has been applied to the enantioselective Au(i) catalyzed dearomatizations of 1-naphthols with allenamides. Stereocontrol is ensured by the intramolecular ion-pairing between the chiral gold-tethered phosphate and an iminium unit, that provides a rigid, well-defined chiral environment to the key electrophilic intermediate.",

author = "Yunliang Yu and Zhenhao Zhang and Arnaud Voituriez and Nicolas Rabasso and Gilles Frison and Angela Marinetti and Xavier Guinchard",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

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doi = "10.1039/d1cc04088j",

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T1 - Enantioselective Au(i)-catalyzed dearomatization of 1-naphthols with allenamides through Tethered Counterion-Directed Catalysis

AU - Yu, Yunliang

AU - Zhang, Zhenhao

AU - Voituriez, Arnaud

AU - Rabasso, Nicolas

AU - Frison, Gilles

AU - Marinetti, Angela

AU - Guinchard, Xavier

PY - 2021/10/21

Y1 - 2021/10/21

N2 - The Tethered Counterion-Directed Catalysis (TCDC) approach has been applied to the enantioselective Au(i) catalyzed dearomatizations of 1-naphthols with allenamides. Stereocontrol is ensured by the intramolecular ion-pairing between the chiral gold-tethered phosphate and an iminium unit, that provides a rigid, well-defined chiral environment to the key electrophilic intermediate.

AB - The Tethered Counterion-Directed Catalysis (TCDC) approach has been applied to the enantioselective Au(i) catalyzed dearomatizations of 1-naphthols with allenamides. Stereocontrol is ensured by the intramolecular ion-pairing between the chiral gold-tethered phosphate and an iminium unit, that provides a rigid, well-defined chiral environment to the key electrophilic intermediate.

UR - https://www.scopus.com/pages/publications/85117235309

U2 - 10.1039/d1cc04088j

DO - 10.1039/d1cc04088j

M3 - Article

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AN - SCOPUS:85117235309

SN - 1359-7345

VL - 57

SP - 10779

EP - 10782

JO - Chemical Communications

JF - Chemical Communications

IS - 82

ER -

Enantioselective Au(i)-catalyzed dearomatization of 1-naphthols with allenamides through Tethered Counterion-Directed Catalysis

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