Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations

Manal Diab; Sébastien Floquet; Mohamed Haouas; Pavel A. Abramov; Xavier López; David Landy; Aurélie Damond; Clément Falaise; Vincent Guérineau; David Touboul; Daoud Naoufal; Emmanuel Cadot

doi:10.1002/ejic.201900602

Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations

Manal Diab
, Sébastien Floquet
, Mohamed Haouas
, Pavel A. Abramov
, Xavier López
, David Landy
, Aurélie Damond
, Clément Falaise
, Vincent Guérineau
, David Touboul
, Daoud Naoufal
, Emmanuel Cadot

Institut Lavoisier de Versailles
Lebanese University
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences
Novosibirsk State University
Universitat Rovira i Virgili
Unité de Chimie Environnementale et Interactions sur le Vivant
Institut de Chimie des Substances Naturelles

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

18 Citations (Scopus)

Résumé

This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.

langue originale	Anglais
Pages (de - à)	3373-3382
Nombre de pages	10
journal	European Journal of Inorganic Chemistry
Volume	2019
Numéro de publication	29
Les DOIs	https://doi.org/10.1002/ejic.201900602
état	Publié - 7 août 2019
Modification externe	Oui

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10.1002/ejic.201900602

Contient cette citation

Diab, M., Floquet, S., Haouas, M., Abramov, P. A., López, X., Landy, D., Damond, A., Falaise, C., Guérineau, V., Touboul, D., Naoufal, D., & Cadot, E. (2019). Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations. European Journal of Inorganic Chemistry, 2019(29), 3373-3382. https://doi.org/10.1002/ejic.201900602

@article{6058f75e15084cb4b1e4484cf2a932b3,

title = "Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations",

abstract = "This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.",

keywords = "Boron, Chaotropes, Cyclodextrins, Host-guest systems, Structure elucidation",

author = "Manal Diab and S{\'e}bastien Floquet and Mohamed Haouas and Abramov, \{Pavel A.\} and Xavier L{\'o}pez and David Landy and Aur{\'e}lie Damond and Cl{\'e}ment Falaise and Vincent Gu{\'e}rineau and David Touboul and Daoud Naoufal and Emmanuel Cadot",

note = "Publisher Copyright: {\textcopyright} 2019 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2019",

month = aug,

day = "7",

doi = "10.1002/ejic.201900602",

language = "English",

volume = "2019",

pages = "3373--3382",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "29",

}

Diab, M, Floquet, S, Haouas, M, Abramov, PA, López, X, Landy, D, Damond, A, Falaise, C, Guérineau, V, Touboul, D, Naoufal, D & Cadot, E 2019, 'Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations', European Journal of Inorganic Chemistry, VOL. 2019, Numéro 29, p. 3373-3382. https://doi.org/10.1002/ejic.201900602

Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations. / Diab, Manal; Floquet, Sébastien; Haouas, Mohamed et al.
Dans: European Journal of Inorganic Chemistry, Vol 2019, Numéro 29, 07.08.2019, p. 3373-3382.

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

TY - JOUR

T1 - Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins

T2 - Synthesis, Solution Studies, and DFT Calculations

AU - Diab, Manal

AU - Floquet, Sébastien

AU - Haouas, Mohamed

AU - Abramov, Pavel A.

AU - López, Xavier

AU - Landy, David

AU - Damond, Aurélie

AU - Falaise, Clément

AU - Guérineau, Vincent

AU - Touboul, David

AU - Naoufal, Daoud

AU - Cadot, Emmanuel

PY - 2019/8/7

Y1 - 2019/8/7

N2 - This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.

AB - This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.

KW - Boron

KW - Chaotropes

KW - Cyclodextrins

KW - Host-guest systems

KW - Structure elucidation

U2 - 10.1002/ejic.201900602

DO - 10.1002/ejic.201900602

M3 - Article

AN - SCOPUS:85069654268

SN - 1434-1948

VL - 2019

SP - 3373

EP - 3382

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 29

ER -

Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations

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