Résumé
The infrared bands line-mixing effects of methane perturbed by nitrogen were discussed at different pressures. The spectral shapes of the ν2, ν4 and ν3 bands were compared at room temperature while the ν3 region was employed for the investigation of thermal effects. The effects of collisions in the ν4 region's spectra were calculated at the room temperature. The Coriolis coupling between ν2 and ν4 vibrational states resulted in the failure of evolution modeling with increasing pressure of absorption.
| langue originale | Anglais |
|---|---|
| Pages (de - à) | 5776-5783 |
| Nombre de pages | 8 |
| journal | Journal of Chemical Physics |
| Volume | 113 |
| Numéro de publication | 14 |
| Les DOIs | |
| état | Publié - 8 oct. 2000 |
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