Free-radical variant for the synthesis of functionalized 1,5-diketones

Kelvin Kau Kiat Goh; Sunggak Kim; Samir Z. Zard

doi:10.1021/ol402213k

Free-radical variant for the synthesis of functionalized 1,5-diketones

Kelvin Kau Kiat Goh
, Sunggak Kim
, Samir Z. Zard

Nanyang Technological University
Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

A free-radical approach for the synthesis of functionalized 1,5-diketones has been accomplished through an effective combination play between alkenylacylphosphonates and keto-xanthates as radical surrogates of enolates and enones, respectively.

langue originale	Anglais
Pages (de - à)	4818-4821
Nombre de pages	4
journal	Organic Letters
Volume	15
Numéro de publication	18
Les DOIs	https://doi.org/10.1021/ol402213k
état	Publié - 20 sept. 2013
Modification externe	Oui

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10.1021/ol402213k

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title = "Free-radical variant for the synthesis of functionalized 1,5-diketones",

abstract = "A free-radical approach for the synthesis of functionalized 1,5-diketones has been accomplished through an effective combination play between alkenylacylphosphonates and keto-xanthates as radical surrogates of enolates and enones, respectively.",

author = "Goh, \{Kelvin Kau Kiat\} and Sunggak Kim and Zard, \{Samir Z.\}",

year = "2013",

month = sep,

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AU - Goh, Kelvin Kau Kiat

AU - Kim, Sunggak

AU - Zard, Samir Z.

PY - 2013/9/20

Y1 - 2013/9/20

N2 - A free-radical approach for the synthesis of functionalized 1,5-diketones has been accomplished through an effective combination play between alkenylacylphosphonates and keto-xanthates as radical surrogates of enolates and enones, respectively.

AB - A free-radical approach for the synthesis of functionalized 1,5-diketones has been accomplished through an effective combination play between alkenylacylphosphonates and keto-xanthates as radical surrogates of enolates and enones, respectively.

UR - https://www.scopus.com/pages/publications/84884570126

U2 - 10.1021/ol402213k

DO - 10.1021/ol402213k

M3 - Article

AN - SCOPUS:84884570126

SN - 1523-7060

VL - 15

SP - 4818

EP - 4821

JO - Organic Letters

JF - Organic Letters

IS - 18

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Free-radical variant for the synthesis of functionalized 1,5-diketones

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