N-(3,5-Di-tert-butylsalicylidene)-4-iodobenzene, a peculiar case of a nonlinear optical photoswitch

Arnaud Spangenberg; Michel Sliwa; Rémi Métivier; Romain Dagnélie; Arnaud Brosseau; Keitaro Nakatani; Robert Pansu; Isabelle Malfant

doi:10.1002/poc.1237

N-(3,5-Di-tert-butylsalicylidene)-4-iodobenzene, a peculiar case of a nonlinear optical photoswitch

Arnaud Spangenberg
, Michel Sliwa
, Rémi Métivier
, Romain Dagnélie
, Arnaud Brosseau
, Keitaro Nakatani
, Robert Pansu
, Isabelle Malfant

Laboratoire de Photophysique et Photochimie Supramoléculaires et Macromoléculaires l'Ecole Normale Supérieure de Cachan
KU Leuven
CNRS UPR 8241

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

7 Citations (Scopus)

Résumé

N-(3,5-Di-tert-butylsalicylidene)-4-iodobenzene (1) is photochromic in the solid state, owing to its ability to yield enol-keto tautomerism. Despite its centrosymmetric structure (P2₁/c), polycrystalline thin films of 1 show second harmonic generation (SHG). Moreover, this SHG can be reversibly switched by light. Investigations using confocal microscopy showed that a morphology change occurs when the fundamental beam of a Ti:sapphire (990 nm, 1.3 ps) is focused on the material, yielding an SHG-active solid.

langue originale	Anglais
Pages (de - à)	992-997
Nombre de pages	6
journal	Journal of Physical Organic Chemistry
Volume	20
Numéro de publication	11
Les DOIs	https://doi.org/10.1002/poc.1237
état	Publié - 1 nov. 2007
Modification externe	Oui

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10.1002/poc.1237

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title = "N-(3,5-Di-tert-butylsalicylidene)-4-iodobenzene, a peculiar case of a nonlinear optical photoswitch",

abstract = "N-(3,5-Di-tert-butylsalicylidene)-4-iodobenzene (1) is photochromic in the solid state, owing to its ability to yield enol-keto tautomerism. Despite its centrosymmetric structure (P21/c), polycrystalline thin films of 1 show second harmonic generation (SHG). Moreover, this SHG can be reversibly switched by light. Investigations using confocal microscopy showed that a morphology change occurs when the fundamental beam of a Ti:sapphire (990 nm, 1.3 ps) is focused on the material, yielding an SHG-active solid.",

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author = "Arnaud Spangenberg and Michel Sliwa and R{\'e}mi M{\'e}tivier and Romain Dagn{\'e}lie and Arnaud Brosseau and Keitaro Nakatani and Robert Pansu and Isabelle Malfant",

year = "2007",

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T1 - N-(3,5-Di-tert-butylsalicylidene)-4-iodobenzene, a peculiar case of a nonlinear optical photoswitch

AU - Spangenberg, Arnaud

AU - Sliwa, Michel

AU - Métivier, Rémi

AU - Dagnélie, Romain

AU - Brosseau, Arnaud

AU - Nakatani, Keitaro

AU - Pansu, Robert

AU - Malfant, Isabelle

PY - 2007/11/1

Y1 - 2007/11/1

N2 - N-(3,5-Di-tert-butylsalicylidene)-4-iodobenzene (1) is photochromic in the solid state, owing to its ability to yield enol-keto tautomerism. Despite its centrosymmetric structure (P21/c), polycrystalline thin films of 1 show second harmonic generation (SHG). Moreover, this SHG can be reversibly switched by light. Investigations using confocal microscopy showed that a morphology change occurs when the fundamental beam of a Ti:sapphire (990 nm, 1.3 ps) is focused on the material, yielding an SHG-active solid.

AB - N-(3,5-Di-tert-butylsalicylidene)-4-iodobenzene (1) is photochromic in the solid state, owing to its ability to yield enol-keto tautomerism. Despite its centrosymmetric structure (P21/c), polycrystalline thin films of 1 show second harmonic generation (SHG). Moreover, this SHG can be reversibly switched by light. Investigations using confocal microscopy showed that a morphology change occurs when the fundamental beam of a Ti:sapphire (990 nm, 1.3 ps) is focused on the material, yielding an SHG-active solid.

KW - Anil

KW - Molecular switch

KW - Nonlinear optics

KW - Photochromism

KW - Second harmonic generation

U2 - 10.1002/poc.1237

DO - 10.1002/poc.1237

M3 - Article

AN - SCOPUS:36348963679

SN - 0894-3230

VL - 20

SP - 992

EP - 997

JO - Journal of Physical Organic Chemistry

JF - Journal of Physical Organic Chemistry

IS - 11

ER -

N-(3,5-Di-tert-butylsalicylidene)-4-iodobenzene, a peculiar case of a nonlinear optical photoswitch

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