Nitrile synthesis through catalyzed cascades involving acid-nitrile exchange

Damien Cartigny; Aurélie Dos Santos; Laurent El Kaïm; Laurence Grimaud; Roland Jacquot; Philippe Marion

doi:10.1055/s-0033-1341227

Nitrile synthesis through catalyzed cascades involving acid-nitrile exchange

Damien Cartigny
, Aurélie Dos Santos
, Laurent El Kaïm
, Laurence Grimaud
, Roland Jacquot
, Philippe Marion

UMI 3464 CNRS-Solvay
Unité Chimie et Procédés
PSL research University & IPSL
Solvay Recherches and Innovation Centre de Lyon

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

Irreversible acid-nitrile exchange reactions using both glutaronitrile and (phenylsulfonyl)acetonitrile may be catalyzed by Lewis acids. Whereas a cyclization towards imides displaces the equilibria in the reaction with dinitriles, a decarboxylation step is involved when using the (phenylsulfonyl)acetonitrile.

langue originale	Anglais
Numéro d'article	SS-2014-T0131-OP
Pages (de - à)	1802-1806
Nombre de pages	5
journal	Synthesis
Volume	46
Numéro de publication	13
Les DOIs	https://doi.org/10.1055/s-0033-1341227
état	Publié - 1 janv. 2014
Modification externe	Oui

Accès au document

10.1055/s-0033-1341227

Autres fichiers et liens

Lien vers la publication dans Scopus

Contient cette citation

@article{7c1b5c63a77542a69938cddc8aabee0a,

title = "Nitrile synthesis through catalyzed cascades involving acid-nitrile exchange",

abstract = "Irreversible acid-nitrile exchange reactions using both glutaronitrile and (phenylsulfonyl)acetonitrile may be catalyzed by Lewis acids. Whereas a cyclization towards imides displaces the equilibria in the reaction with dinitriles, a decarboxylation step is involved when using the (phenylsulfonyl)acetonitrile.",

keywords = "Lewis acids, acylation, carboxylic acids, imides, nitriles",

author = "Damien Cartigny and \{Dos Santos\}, Aur{\'e}lie and \{El Ka{\"i}m\}, Laurent and Laurence Grimaud and Roland Jacquot and Philippe Marion",

year = "2014",

month = jan,

day = "1",

doi = "10.1055/s-0033-1341227",

language = "English",

volume = "46",

pages = "1802--1806",

journal = "Synthesis",

issn = "0039-7881",

number = "13",

}

TY - JOUR

T1 - Nitrile synthesis through catalyzed cascades involving acid-nitrile exchange

AU - Cartigny, Damien

AU - Dos Santos, Aurélie

AU - El Kaïm, Laurent

AU - Grimaud, Laurence

AU - Jacquot, Roland

AU - Marion, Philippe

PY - 2014/1/1

Y1 - 2014/1/1

N2 - Irreversible acid-nitrile exchange reactions using both glutaronitrile and (phenylsulfonyl)acetonitrile may be catalyzed by Lewis acids. Whereas a cyclization towards imides displaces the equilibria in the reaction with dinitriles, a decarboxylation step is involved when using the (phenylsulfonyl)acetonitrile.

AB - Irreversible acid-nitrile exchange reactions using both glutaronitrile and (phenylsulfonyl)acetonitrile may be catalyzed by Lewis acids. Whereas a cyclization towards imides displaces the equilibria in the reaction with dinitriles, a decarboxylation step is involved when using the (phenylsulfonyl)acetonitrile.

KW - Lewis acids

KW - acylation

KW - carboxylic acids

KW - imides

KW - nitriles

UR - https://www.scopus.com/pages/publications/84903280050

U2 - 10.1055/s-0033-1341227

DO - 10.1055/s-0033-1341227

M3 - Article

AN - SCOPUS:84903280050

SN - 0039-7881

VL - 46

SP - 1802

EP - 1806

JO - Synthesis

JF - Synthesis

IS - 13

M1 - SS-2014-T0131-OP

ER -

Nitrile synthesis through catalyzed cascades involving acid-nitrile exchange

Résumé

Accès au document

Autres fichiers et liens

Empreinte digitale

Contient cette citation