O-arylative Passerini reactions

Laurent El Kaim; Marie Gizolme; Laurence Grimaud

doi:10.1021/ol0617502

O-arylative Passerini reactions

Laurent El Kaim
, Marie Gizolme
, Laurence Grimaud

Unité Chimie et Procédés

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

78 Citations (Scopus)

Résumé

(Chemical Equation Presented) The three-component addition of isocyanides to phenol derivatives and aldehydes proceeds easily in methanol to form O-arylated compounds in a new Passerini-type reaction. The key step of the conversion lies in an irreversible Smiles rearrangement of intermediate phenoxyimidate adducts. It represents the first use of a Smiles rearrangement in a Passerini reaction.

langue originale	Anglais
Pages (de - à)	5021-5023
Nombre de pages	3
journal	Organic Letters
Volume	8
Numéro de publication	22
Les DOIs	https://doi.org/10.1021/ol0617502
état	Publié - 26 oct. 2006
Modification externe	Oui

Accès au document

10.1021/ol0617502

Contient cette citation

@article{149054c60dff4c90a4cd24f020ec7e2d,

title = "O-arylative Passerini reactions",

abstract = "(Chemical Equation Presented) The three-component addition of isocyanides to phenol derivatives and aldehydes proceeds easily in methanol to form O-arylated compounds in a new Passerini-type reaction. The key step of the conversion lies in an irreversible Smiles rearrangement of intermediate phenoxyimidate adducts. It represents the first use of a Smiles rearrangement in a Passerini reaction.",

author = "\{El Kaim\}, Laurent and Marie Gizolme and Laurence Grimaud",

year = "2006",

month = oct,

day = "26",

doi = "10.1021/ol0617502",

language = "English",

volume = "8",

pages = "5021--5023",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "22",

}

TY - JOUR

T1 - O-arylative Passerini reactions

AU - El Kaim, Laurent

AU - Gizolme, Marie

AU - Grimaud, Laurence

PY - 2006/10/26

Y1 - 2006/10/26

N2 - (Chemical Equation Presented) The three-component addition of isocyanides to phenol derivatives and aldehydes proceeds easily in methanol to form O-arylated compounds in a new Passerini-type reaction. The key step of the conversion lies in an irreversible Smiles rearrangement of intermediate phenoxyimidate adducts. It represents the first use of a Smiles rearrangement in a Passerini reaction.

AB - (Chemical Equation Presented) The three-component addition of isocyanides to phenol derivatives and aldehydes proceeds easily in methanol to form O-arylated compounds in a new Passerini-type reaction. The key step of the conversion lies in an irreversible Smiles rearrangement of intermediate phenoxyimidate adducts. It represents the first use of a Smiles rearrangement in a Passerini reaction.

U2 - 10.1021/ol0617502

DO - 10.1021/ol0617502

M3 - Article

AN - SCOPUS:33750929343

SN - 1523-7060

VL - 8

SP - 5021

EP - 5023

JO - Organic Letters

JF - Organic Letters

IS - 22

ER -

O-arylative Passerini reactions

Résumé

Accès au document

Empreinte digitale

Contient cette citation