On the mechanism of reduction of dithiocarbonates (xanthates) with tributylstannane

Derek H.R. Barton; David Crich; Antonius Löbberding; Samir Z. Zard

doi:10.1039/C39850000646

On the mechanism of reduction of dithiocarbonates (xanthates) with tributylstannane

Derek H.R. Barton
, David Crich
, Antonius Löbberding
, Samir Z. Zard

Institut de Chimie des Substances Naturelles

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

Competition experiments with various dithiocarbonates show that the deoxygenation occurs by addition of stannyl radicals to give (2) followed by fragmentation rather than by direct S_H2 attack on sulphide sulphur.

langue originale	Anglais
Pages (de - à)	646-647
Nombre de pages	2
journal	Journal of the Chemical Society, Chemical Communications
Numéro de publication	10
Les DOIs	https://doi.org/10.1039/C39850000646
état	Publié - 1 janv. 1985
Modification externe	Oui

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10.1039/C39850000646

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title = "On the mechanism of reduction of dithiocarbonates (xanthates) with tributylstannane",

abstract = "Competition experiments with various dithiocarbonates show that the deoxygenation occurs by addition of stannyl radicals to give (2) followed by fragmentation rather than by direct SH2 attack on sulphide sulphur.",

author = "Barton, \{Derek H.R.\} and David Crich and Antonius L{\"o}bberding and Zard, \{Samir Z.\}",

year = "1985",

month = jan,

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doi = "10.1039/C39850000646",

language = "English",

pages = "646--647",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

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T1 - On the mechanism of reduction of dithiocarbonates (xanthates) with tributylstannane

AU - Barton, Derek H.R.

AU - Crich, David

AU - Löbberding, Antonius

AU - Zard, Samir Z.

PY - 1985/1/1

Y1 - 1985/1/1

N2 - Competition experiments with various dithiocarbonates show that the deoxygenation occurs by addition of stannyl radicals to give (2) followed by fragmentation rather than by direct SH2 attack on sulphide sulphur.

AB - Competition experiments with various dithiocarbonates show that the deoxygenation occurs by addition of stannyl radicals to give (2) followed by fragmentation rather than by direct SH2 attack on sulphide sulphur.

U2 - 10.1039/C39850000646

DO - 10.1039/C39850000646

M3 - Article

AN - SCOPUS:24744466816

SN - 0022-4936

SP - 646

EP - 647

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 10

ER -

On the mechanism of reduction of dithiocarbonates (xanthates) with tributylstannane

Résumé

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