Organochromium/organoiron dipoles comprising (η6-arene)chromium and (η5-cyclohexadienyl)iron(1+) complexes linked with conjugated spacers

Jean Philippe Tranchier; René Chavignon; Damien Prim; Audrey Auffrant; Jose Giner Planas; Françoise Rose-Munch; Eric Rose; G. Richard Stephenson

doi:10.1016/S0040-4039(01)00445-2

Organochromium/organoiron dipoles comprising (η⁶-arene)chromium and (η⁵-cyclohexadienyl)iron(1+) complexes linked with conjugated spacers

Jean Philippe Tranchier
, René Chavignon
, Damien Prim
, Audrey Auffrant
, Jose Giner Planas
, Françoise Rose-Munch
, Eric Rose
, G. Richard Stephenson

CNRS
University of East Anglia

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

The synthesis of novel bimetallic organochromium/organoiron monocation dipoles comprising π-conjugated complexes linked with conjugated spacers has been performed utilising Stille and Sonogashira coupling reactions. This work establishes a general strategy for the synthesis of mixed-metal chromium/dipole complexes for evaluation for nonlinear optical effects by hyper-Rayleigh scattering.

langue originale	Anglais
Pages (de - à)	3311-3313
Nombre de pages	3
journal	Tetrahedron Letters
Volume	42
Numéro de publication	19
Les DOIs	https://doi.org/10.1016/S0040-4039(01)00445-2
état	Publié - 7 mai 2001

Accès au document

10.1016/S0040-4039(01)00445-2

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Contient cette citation

@article{b21d444743b449a893ffff0f04cecdc9,

title = "Organochromium/organoiron dipoles comprising (η6-arene)chromium and (η5-cyclohexadienyl)iron(1+) complexes linked with conjugated spacers",

abstract = "The synthesis of novel bimetallic organochromium/organoiron monocation dipoles comprising π-conjugated complexes linked with conjugated spacers has been performed utilising Stille and Sonogashira coupling reactions. This work establishes a general strategy for the synthesis of mixed-metal chromium/dipole complexes for evaluation for nonlinear optical effects by hyper-Rayleigh scattering.",

keywords = "Alkyne, Bimetallic dipoles, Nonlinear optics, Thiophene, Tricarbonylarenechromium, Tricarbonylcyclohexadienyliron",

author = "Tranchier, \{Jean Philippe\} and Ren{\'e} Chavignon and Damien Prim and Audrey Auffrant and Planas, \{Jose Giner\} and Fran{\c c}oise Rose-Munch and Eric Rose and Stephenson, \{G. Richard\}",

year = "2001",

month = may,

day = "7",

doi = "10.1016/S0040-4039(01)00445-2",

language = "English",

volume = "42",

pages = "3311--3313",

journal = "Tetrahedron Letters",

issn = "0040-4039",

number = "19",

}

TY - JOUR

T1 - Organochromium/organoiron dipoles comprising (η6-arene)chromium and (η5-cyclohexadienyl)iron(1+) complexes linked with conjugated spacers

AU - Tranchier, Jean Philippe

AU - Chavignon, René

AU - Prim, Damien

AU - Auffrant, Audrey

AU - Planas, Jose Giner

AU - Rose-Munch, Françoise

AU - Rose, Eric

AU - Stephenson, G. Richard

PY - 2001/5/7

Y1 - 2001/5/7

N2 - The synthesis of novel bimetallic organochromium/organoiron monocation dipoles comprising π-conjugated complexes linked with conjugated spacers has been performed utilising Stille and Sonogashira coupling reactions. This work establishes a general strategy for the synthesis of mixed-metal chromium/dipole complexes for evaluation for nonlinear optical effects by hyper-Rayleigh scattering.

AB - The synthesis of novel bimetallic organochromium/organoiron monocation dipoles comprising π-conjugated complexes linked with conjugated spacers has been performed utilising Stille and Sonogashira coupling reactions. This work establishes a general strategy for the synthesis of mixed-metal chromium/dipole complexes for evaluation for nonlinear optical effects by hyper-Rayleigh scattering.

KW - Alkyne

KW - Bimetallic dipoles

KW - Nonlinear optics

KW - Thiophene

KW - Tricarbonylarenechromium

KW - Tricarbonylcyclohexadienyliron

UR - https://www.scopus.com/pages/publications/0035821318

U2 - 10.1016/S0040-4039(01)00445-2

DO - 10.1016/S0040-4039(01)00445-2

M3 - Article

AN - SCOPUS:0035821318

SN - 0040-4039

VL - 42

SP - 3311

EP - 3313

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 19