Organophotocatalysis Enables the Synthesis of gem-Fluorophosphonate Alkenes

Solène Morand; William Lecroq; Philippe Jubault; Sami Lakhdar; Jean Philippe Bouillon; Samuel Couve-Bonnaire

doi:10.1021/acs.orglett.2c03366

Organophotocatalysis Enables the Synthesis of gem-Fluorophosphonate Alkenes

Solène Morand
, William Lecroq
, Philippe Jubault
, Sami Lakhdar
, Jean Philippe Bouillon
, Samuel Couve-Bonnaire

Normandie Univ
CNRS
Université Paul Sabatier

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

11 Citations (Scopus)

Résumé

gem-Bromofluoroalkenes have been combined with phosphite under irradiation, in the presence of Fukuzumi's catalyst (9-mesityl-10-methylacridinium perchlorate) as an organic photocatalyst, to provide valuable gem-fluorophosphonate derivatives, known as stable mimics of phosphates. The desired products were obtained in good to excellent yields, and the reaction showed very good chemical tolerance.

langue originale	Anglais
Pages (de - à)	8343-8347
Nombre de pages	5
journal	Organic Letters
Volume	24
Numéro de publication	45
Les DOIs	https://doi.org/10.1021/acs.orglett.2c03366
état	Publié - 18 nov. 2022
Modification externe	Oui

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10.1021/acs.orglett.2c03366

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title = "Organophotocatalysis Enables the Synthesis of gem-Fluorophosphonate Alkenes",

abstract = "gem-Bromofluoroalkenes have been combined with phosphite under irradiation, in the presence of Fukuzumi's catalyst (9-mesityl-10-methylacridinium perchlorate) as an organic photocatalyst, to provide valuable gem-fluorophosphonate derivatives, known as stable mimics of phosphates. The desired products were obtained in good to excellent yields, and the reaction showed very good chemical tolerance.",

author = "Sol{\`e}ne Morand and William Lecroq and Philippe Jubault and Sami Lakhdar and Bouillon, \{Jean Philippe\} and Samuel Couve-Bonnaire",

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T1 - Organophotocatalysis Enables the Synthesis of gem-Fluorophosphonate Alkenes

AU - Morand, Solène

AU - Lecroq, William

AU - Jubault, Philippe

AU - Lakhdar, Sami

AU - Bouillon, Jean Philippe

AU - Couve-Bonnaire, Samuel

PY - 2022/11/18

Y1 - 2022/11/18

N2 - gem-Bromofluoroalkenes have been combined with phosphite under irradiation, in the presence of Fukuzumi's catalyst (9-mesityl-10-methylacridinium perchlorate) as an organic photocatalyst, to provide valuable gem-fluorophosphonate derivatives, known as stable mimics of phosphates. The desired products were obtained in good to excellent yields, and the reaction showed very good chemical tolerance.

AB - gem-Bromofluoroalkenes have been combined with phosphite under irradiation, in the presence of Fukuzumi's catalyst (9-mesityl-10-methylacridinium perchlorate) as an organic photocatalyst, to provide valuable gem-fluorophosphonate derivatives, known as stable mimics of phosphates. The desired products were obtained in good to excellent yields, and the reaction showed very good chemical tolerance.

UR - https://www.scopus.com/pages/publications/85141950856

U2 - 10.1021/acs.orglett.2c03366

DO - 10.1021/acs.orglett.2c03366

M3 - Article

C2 - 36350256

AN - SCOPUS:85141950856

SN - 1523-7060

VL - 24

SP - 8343

EP - 8347

JO - Organic Letters

JF - Organic Letters

IS - 45

ER -

Organophotocatalysis Enables the Synthesis of gem-Fluorophosphonate Alkenes

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