Pincer versus pseudopincer: Isomerism in palladium(ii) complexes bearing κ3C,S,C ligands

Jan Christopher Bernhammer; Gilles Frison; Han Vinh Huynh

doi:10.1039/c4dt01047g

Pincer versus pseudopincer: Isomerism in palladium(ii) complexes bearing κ³C,S,C ligands

Jan Christopher Bernhammer
, Gilles Frison
, Han Vinh Huynh

École Polytechnique

National University of Singapore
CNRS

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

In NHC pincer complexes incorporating a hemilabile donor site, there exists an equilibrium between the true pincer form and a pseudopincer coordination isomer. The influence of the NHC moieties on this isomerism has been studied by DFT calculations.

langue originale	Anglais
Pages (de - à)	8591-8594
Nombre de pages	4
journal	Dalton Transactions
Volume	43
Numéro de publication	23
Les DOIs	https://doi.org/10.1039/c4dt01047g
état	Publié - 21 juin 2014

Accès au document

10.1039/c4dt01047g

Autres fichiers et liens

Lien vers la publication dans Scopus

Contient cette citation

@article{4aa8de03a69f4ca88c04990521624407,

title = "Pincer versus pseudopincer: Isomerism in palladium(ii) complexes bearing κ3C,S,C ligands",

abstract = "In NHC pincer complexes incorporating a hemilabile donor site, there exists an equilibrium between the true pincer form and a pseudopincer coordination isomer. The influence of the NHC moieties on this isomerism has been studied by DFT calculations.",

author = "Bernhammer, \{Jan Christopher\} and Gilles Frison and Huynh, \{Han Vinh\}",

year = "2014",

month = jun,

day = "21",

doi = "10.1039/c4dt01047g",

language = "English",

volume = "43",

pages = "8591--8594",

journal = "Dalton Transactions",

issn = "1477-9226",

number = "23",

}

TY - JOUR

T1 - Pincer versus pseudopincer

T2 - Isomerism in palladium(ii) complexes bearing κ3C,S,C ligands

AU - Bernhammer, Jan Christopher

AU - Frison, Gilles

AU - Huynh, Han Vinh

PY - 2014/6/21

Y1 - 2014/6/21

N2 - In NHC pincer complexes incorporating a hemilabile donor site, there exists an equilibrium between the true pincer form and a pseudopincer coordination isomer. The influence of the NHC moieties on this isomerism has been studied by DFT calculations.

AB - In NHC pincer complexes incorporating a hemilabile donor site, there exists an equilibrium between the true pincer form and a pseudopincer coordination isomer. The influence of the NHC moieties on this isomerism has been studied by DFT calculations.

UR - https://www.scopus.com/pages/publications/84901257313

U2 - 10.1039/c4dt01047g

DO - 10.1039/c4dt01047g

M3 - Article

AN - SCOPUS:84901257313

SN - 1477-9226

VL - 43

SP - 8591

EP - 8594

JO - Dalton Transactions

JF - Dalton Transactions

IS - 23