Polarization and wavelength dependent nonlinear optical properties of a photo-switchable organic crystal

Michel Sliwa; Keitaro Nakatani; Tsuyoshi Asahi; Pascal G. Lacroix; Robert B. Pansu; Hiroshi Masuhara

doi:10.1016/j.cplett.2007.02.001

Polarization and wavelength dependent nonlinear optical properties of a photo-switchable organic crystal

Michel Sliwa
, Keitaro Nakatani
, Tsuyoshi Asahi
, Pascal G. Lacroix
, Robert B. Pansu
, Hiroshi Masuhara

Laboratoire de Photophysique et Photochimie Supramoléculaires et Macromoléculaires l'Ecole Normale Supérieure de Cachan
Osaka University
CNRS UPR 8241

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

Polarization dependence of the second harmonic generation (SHG) was studied on a single crystal of the photochromic N-(3,5-di-tert-butylsalicylidene)-4-aminopyridine (4P). The optimal polarization condition for SHG is obtained when both the fundamental and second harmonic waves are parallel to the main axis of the crystal. This experimental result was correlated with calculations based on X-ray diffraction structure. Also, wavelength dependent studies showed that SHG-switching on near-UV irradiation could be tuned by utilizing the absorption and resonance effects of the photo-induced species.

langue originale	Anglais
Pages (de - à)	212-217
Nombre de pages	6
journal	Chemical Physics Letters
Volume	437
Numéro de publication	4-6
Les DOIs	https://doi.org/10.1016/j.cplett.2007.02.001
état	Publié - 2 avr. 2007
Modification externe	Oui

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10.1016/j.cplett.2007.02.001

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title = "Polarization and wavelength dependent nonlinear optical properties of a photo-switchable organic crystal",

abstract = "Polarization dependence of the second harmonic generation (SHG) was studied on a single crystal of the photochromic N-(3,5-di-tert-butylsalicylidene)-4-aminopyridine (4P). The optimal polarization condition for SHG is obtained when both the fundamental and second harmonic waves are parallel to the main axis of the crystal. This experimental result was correlated with calculations based on X-ray diffraction structure. Also, wavelength dependent studies showed that SHG-switching on near-UV irradiation could be tuned by utilizing the absorption and resonance effects of the photo-induced species.",

author = "Michel Sliwa and Keitaro Nakatani and Tsuyoshi Asahi and Lacroix, \{Pascal G.\} and Pansu, \{Robert B.\} and Hiroshi Masuhara",

year = "2007",

month = apr,

day = "2",

doi = "10.1016/j.cplett.2007.02.001",

language = "English",

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journal = "Chemical Physics Letters",

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T1 - Polarization and wavelength dependent nonlinear optical properties of a photo-switchable organic crystal

AU - Sliwa, Michel

AU - Nakatani, Keitaro

AU - Asahi, Tsuyoshi

AU - Lacroix, Pascal G.

AU - Pansu, Robert B.

AU - Masuhara, Hiroshi

PY - 2007/4/2

Y1 - 2007/4/2

N2 - Polarization dependence of the second harmonic generation (SHG) was studied on a single crystal of the photochromic N-(3,5-di-tert-butylsalicylidene)-4-aminopyridine (4P). The optimal polarization condition for SHG is obtained when both the fundamental and second harmonic waves are parallel to the main axis of the crystal. This experimental result was correlated with calculations based on X-ray diffraction structure. Also, wavelength dependent studies showed that SHG-switching on near-UV irradiation could be tuned by utilizing the absorption and resonance effects of the photo-induced species.

AB - Polarization dependence of the second harmonic generation (SHG) was studied on a single crystal of the photochromic N-(3,5-di-tert-butylsalicylidene)-4-aminopyridine (4P). The optimal polarization condition for SHG is obtained when both the fundamental and second harmonic waves are parallel to the main axis of the crystal. This experimental result was correlated with calculations based on X-ray diffraction structure. Also, wavelength dependent studies showed that SHG-switching on near-UV irradiation could be tuned by utilizing the absorption and resonance effects of the photo-induced species.

U2 - 10.1016/j.cplett.2007.02.001

DO - 10.1016/j.cplett.2007.02.001

M3 - Article

AN - SCOPUS:33947287930

SN - 0009-2614

VL - 437

SP - 212

EP - 217

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4-6

ER -

Polarization and wavelength dependent nonlinear optical properties of a photo-switchable organic crystal

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