Pyrazine-Fused Bis(tetrathiafulvalenes)

Khalid Lahlil; Alec Moradpour; Claude Merienne; Christopher Bowlas

doi:10.1021/jo00105a018

Pyrazine-Fused Bis(tetrathiafulvalenes)

Khalid Lahlil
, Alec Moradpour
, Claude Merienne
, Christopher Bowlas

Laboratoire de Physique des Solides
Université Paris-Saclay
CNRS UPR 8241
Laboratoire de Physique des Solides
Laboratoire de Chimie et Physico-Chimie des Milieux Structurés

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

The TTF-like bidentate sulfur nucleophiles 13a,b have been prepared from the corresponding 4,5-dialkyl-1,3-dithiole S-oxides 11a,b, obtained by the oxidation of the parent 1,3-dithioles 10a,b. The aromatic nucleophilic substitutions of tetrachloropyrazine by these nucleophiles 13a,b yield, in a single step, the unsymmetrically substituted pyrazino-TTF 8 or the pyrazine-fused bis-TTF 9a,b depending on the stoeichiometries of the reactions. The electrochemical properties of these new donors, obtained by cyclic voltammetry, are also reported.

langue originale	Anglais
Pages (de - à)	8030-8033
Nombre de pages	4
journal	Journal of Organic Chemistry
Volume	59
Numéro de publication	26
Les DOIs	https://doi.org/10.1021/jo00105a018
état	Publié - 1 déc. 1994
Modification externe	Oui

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10.1021/jo00105a018

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title = "Pyrazine-Fused Bis(tetrathiafulvalenes)",

abstract = "The TTF-like bidentate sulfur nucleophiles 13a,b have been prepared from the corresponding 4,5-dialkyl-1,3-dithiole S-oxides 11a,b, obtained by the oxidation of the parent 1,3-dithioles 10a,b. The aromatic nucleophilic substitutions of tetrachloropyrazine by these nucleophiles 13a,b yield, in a single step, the unsymmetrically substituted pyrazino-TTF 8 or the pyrazine-fused bis-TTF 9a,b depending on the stoeichiometries of the reactions. The electrochemical properties of these new donors, obtained by cyclic voltammetry, are also reported.",

author = "Khalid Lahlil and Alec Moradpour and Claude Merienne and Christopher Bowlas",

year = "1994",

month = dec,

day = "1",

doi = "10.1021/jo00105a018",

language = "English",

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journal = "Journal of Organic Chemistry",

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T1 - Pyrazine-Fused Bis(tetrathiafulvalenes)

AU - Lahlil, Khalid

AU - Moradpour, Alec

AU - Merienne, Claude

AU - Bowlas, Christopher

PY - 1994/12/1

Y1 - 1994/12/1

N2 - The TTF-like bidentate sulfur nucleophiles 13a,b have been prepared from the corresponding 4,5-dialkyl-1,3-dithiole S-oxides 11a,b, obtained by the oxidation of the parent 1,3-dithioles 10a,b. The aromatic nucleophilic substitutions of tetrachloropyrazine by these nucleophiles 13a,b yield, in a single step, the unsymmetrically substituted pyrazino-TTF 8 or the pyrazine-fused bis-TTF 9a,b depending on the stoeichiometries of the reactions. The electrochemical properties of these new donors, obtained by cyclic voltammetry, are also reported.

AB - The TTF-like bidentate sulfur nucleophiles 13a,b have been prepared from the corresponding 4,5-dialkyl-1,3-dithiole S-oxides 11a,b, obtained by the oxidation of the parent 1,3-dithioles 10a,b. The aromatic nucleophilic substitutions of tetrachloropyrazine by these nucleophiles 13a,b yield, in a single step, the unsymmetrically substituted pyrazino-TTF 8 or the pyrazine-fused bis-TTF 9a,b depending on the stoeichiometries of the reactions. The electrochemical properties of these new donors, obtained by cyclic voltammetry, are also reported.

U2 - 10.1021/jo00105a018

DO - 10.1021/jo00105a018

M3 - Article

AN - SCOPUS:4043092006

SN - 0022-3263

VL - 59

SP - 8030

EP - 8033

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 26

ER -

Pyrazine-Fused Bis(tetrathiafulvalenes)

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