Redox-active phosphines: Synthesis and crystal structures of palladium(ii) complexes of a metallaphosphine in two different oxidation states

Ayham Tohmé; Stéphanie Labouille; Thierry Roisnel; Vincent Dorcet; Duncan Carmichael; Frédéric Paul

doi:10.1039/c4dt00455h

Redox-active phosphines: Synthesis and crystal structures of palladium(ii) complexes of a metallaphosphine in two different oxidation states

Ayham Tohmé
, Stéphanie Labouille
, Thierry Roisnel
, Vincent Dorcet
, Duncan Carmichael
, Frédéric Paul

University of Rennes
CNRS

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

The redox-active metallaphosphine [Fe(dppe)(η⁵-C ₅Me₅)(CC-PPh₂)] reacts with [Pd(1,5-cod)Cl ₂] to give mono- and bis-phosphine coordinated palladium centres as a function of stoichiometry, and these complexes provide a stable redox-active platform which allows reversible one-electron {Fe(ii)→Fe(iii)⁺} oxidations within the palladium coordination sphere.

langue originale	Anglais
Pages (de - à)	7002-7005
Nombre de pages	4
journal	Dalton Transactions
Volume	43
Numéro de publication	19
Les DOIs	https://doi.org/10.1039/c4dt00455h
état	Publié - 21 mai 2014
Modification externe	Oui

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10.1039/c4dt00455h

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title = "Redox-active phosphines: Synthesis and crystal structures of palladium(ii) complexes of a metallaphosphine in two different oxidation states",

abstract = "The redox-active metallaphosphine [Fe(dppe)(η5-C 5Me5)(CC-PPh2)] reacts with [Pd(1,5-cod)Cl 2] to give mono- and bis-phosphine coordinated palladium centres as a function of stoichiometry, and these complexes provide a stable redox-active platform which allows reversible one-electron \{Fe(ii)→Fe(iii)+\} oxidations within the palladium coordination sphere.",

author = "Ayham Tohm{\'e} and St{\'e}phanie Labouille and Thierry Roisnel and Vincent Dorcet and Duncan Carmichael and Fr{\'e}d{\'e}ric Paul",

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T2 - Synthesis and crystal structures of palladium(ii) complexes of a metallaphosphine in two different oxidation states

AU - Tohmé, Ayham

AU - Labouille, Stéphanie

AU - Roisnel, Thierry

AU - Dorcet, Vincent

AU - Carmichael, Duncan

AU - Paul, Frédéric

PY - 2014/5/21

Y1 - 2014/5/21

N2 - The redox-active metallaphosphine [Fe(dppe)(η5-C 5Me5)(CC-PPh2)] reacts with [Pd(1,5-cod)Cl 2] to give mono- and bis-phosphine coordinated palladium centres as a function of stoichiometry, and these complexes provide a stable redox-active platform which allows reversible one-electron {Fe(ii)→Fe(iii)+} oxidations within the palladium coordination sphere.

AB - The redox-active metallaphosphine [Fe(dppe)(η5-C 5Me5)(CC-PPh2)] reacts with [Pd(1,5-cod)Cl 2] to give mono- and bis-phosphine coordinated palladium centres as a function of stoichiometry, and these complexes provide a stable redox-active platform which allows reversible one-electron {Fe(ii)→Fe(iii)+} oxidations within the palladium coordination sphere.

U2 - 10.1039/c4dt00455h

DO - 10.1039/c4dt00455h

M3 - Article

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EP - 7005

JO - Dalton Transactions

JF - Dalton Transactions

IS - 19

ER -

Redox-active phosphines: Synthesis and crystal structures of palladium(ii) complexes of a metallaphosphine in two different oxidation states

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