Reductive formylation of oximes; an approach to the synthesis of vinyl isonitriles

Derek HR Barton; Timothy Bowles; Suren Husinec; Judith E. Forbes; Antonia Llobera; Alexander EA Porter; Samir Z. Zard

doi:10.1016/0040-4039(88)85157-8

Reductive formylation of oximes; an approach to the synthesis of vinyl isonitriles

Derek HR Barton
, Timothy Bowles
, Suren Husinec
, Judith E. Forbes
, Antonia Llobera
, Alexander EA Porter
, Samir Z. Zard

Texas A&M University
Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

44 Citations (Scopus)

Résumé

Reduction of ketoximes using anhydrous titanium-(III)-acetate in the presence of mixed formic-acetic anhydride yields N-formyl enamines which may be dehydrated to vinyl isonitriles.

langue originale	Anglais
Pages (de - à)	3343-3346
Nombre de pages	4
journal	Tetrahedron Letters
Volume	29
Numéro de publication	27
Les DOIs	https://doi.org/10.1016/0040-4039(88)85157-8
état	Publié - 1 janv. 1988
Modification externe	Oui

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10.1016/0040-4039(88)85157-8

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@article{4e97e781b523486c8b1229790d86e8d3,

title = "Reductive formylation of oximes; an approach to the synthesis of vinyl isonitriles",

abstract = "Reduction of ketoximes using anhydrous titanium-(III)-acetate in the presence of mixed formic-acetic anhydride yields N-formyl enamines which may be dehydrated to vinyl isonitriles.",

author = "Barton, \{Derek HR\} and Timothy Bowles and Suren Husinec and Forbes, \{Judith E.\} and Antonia Llobera and Porter, \{Alexander EA\} and Zard, \{Samir Z.\}",

year = "1988",

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doi = "10.1016/0040-4039(88)85157-8",

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T1 - Reductive formylation of oximes; an approach to the synthesis of vinyl isonitriles

AU - Barton, Derek HR

AU - Bowles, Timothy

AU - Husinec, Suren

AU - Forbes, Judith E.

AU - Llobera, Antonia

AU - Porter, Alexander EA

AU - Zard, Samir Z.

PY - 1988/1/1

Y1 - 1988/1/1

N2 - Reduction of ketoximes using anhydrous titanium-(III)-acetate in the presence of mixed formic-acetic anhydride yields N-formyl enamines which may be dehydrated to vinyl isonitriles.

AB - Reduction of ketoximes using anhydrous titanium-(III)-acetate in the presence of mixed formic-acetic anhydride yields N-formyl enamines which may be dehydrated to vinyl isonitriles.

U2 - 10.1016/0040-4039(88)85157-8

DO - 10.1016/0040-4039(88)85157-8

M3 - Article

AN - SCOPUS:0001682833

SN - 0040-4039

VL - 29

SP - 3343

EP - 3346

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 27

ER -

Reductive formylation of oximes; an approach to the synthesis of vinyl isonitriles

Résumé

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