Reductive Passerini/Tsuji-Trost strategy towards β,γ-unsaturated amides

Aurélie Dos Santos; Laurent El Kaïm

doi:10.1055/s-0033-1340187

Reductive Passerini/Tsuji-Trost strategy towards β,γ-unsaturated amides

Aurélie Dos Santos
, Laurent El Kaïm

Unité Chimie et Procédés

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

The Passerini reaction of α,β-unsaturated aldehydes with formic acid followed by a reductive Tsuji-Trost reaction affords β,γ- unsaturated amides. The overall process may be viewed as a one-carbon homologation of unsaturated aldehydes into amides.

langue originale	Anglais
Numéro d'article	st-2014-d0326-l
Pages (de - à)	1901-1903
Nombre de pages	3
journal	Synlett
Volume	25
Numéro de publication	13
Les DOIs	https://doi.org/10.1055/s-0033-1340187
état	Publié - 1 janv. 2014
Modification externe	Oui

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10.1055/s-0033-1340187

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title = "Reductive Passerini/Tsuji-Trost strategy towards β,γ-unsaturated amides",

abstract = "The Passerini reaction of α,β-unsaturated aldehydes with formic acid followed by a reductive Tsuji-Trost reaction affords β,γ- unsaturated amides. The overall process may be viewed as a one-carbon homologation of unsaturated aldehydes into amides.",

keywords = "allyl complexes, multicomponent reaction, palladium, reduction, tandem reaction",

author = "\{Dos Santos\}, Aur{\'e}lie and \{El Ka{\"i}m\}, Laurent",

year = "2014",

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doi = "10.1055/s-0033-1340187",

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journal = "Synlett",

issn = "0936-5214",

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AU - Dos Santos, Aurélie

AU - El Kaïm, Laurent

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N2 - The Passerini reaction of α,β-unsaturated aldehydes with formic acid followed by a reductive Tsuji-Trost reaction affords β,γ- unsaturated amides. The overall process may be viewed as a one-carbon homologation of unsaturated aldehydes into amides.

AB - The Passerini reaction of α,β-unsaturated aldehydes with formic acid followed by a reductive Tsuji-Trost reaction affords β,γ- unsaturated amides. The overall process may be viewed as a one-carbon homologation of unsaturated aldehydes into amides.

KW - allyl complexes

KW - multicomponent reaction

KW - palladium

KW - reduction

KW - tandem reaction

U2 - 10.1055/s-0033-1340187

DO - 10.1055/s-0033-1340187

M3 - Article

AN - SCOPUS:84905483733

SN - 0936-5214

VL - 25

SP - 1901

EP - 1903

JO - Synlett

JF - Synlett

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M1 - st-2014-d0326-l

ER -

Reductive Passerini/Tsuji-Trost strategy towards β,γ-unsaturated amides

Résumé

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